Cycloolefin-copolymere:一个新的班级透明thermoplaste†

H. Cherdron, M.‐J. Brekner, F. Osan
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引用次数: 130

摘要

对茂金属基环烯烃(COC)的聚合工艺和性能改性的研究表明,这种单体-催化剂组合可以合成一类新的透明热塑性聚合物。茂金属催化为改变共聚物的组成和微观结构提供了很多机会。聚合物光谱的宽度可以通过聚合物改性进一步扩大,使这种新型热塑性塑料的许多应用成为可能。本文讨论了控制COC族结构和性能的关键参数
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Cycloolefin-copolymere: Eine neue klasse transparenter thermoplaste†
Investigation of the polymerization process and property modification of metallocene-based cycloolefin (COC) shows that this monomer-catalyst combination enables synthesis of a new class of transparent thermoplastic polymers. Metallocene catalysis offers much opportunity to vary the composition and microstructure of the copolymers. The breadth of the polymer spectrum which can be further widened by polymer modification enables many applications for this new class of thermoplastics. The key parameters that control structure and properties in the COC family are discussed in this paper
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