碳杂化材料制造反应器设计

Sung Kim, Megha Chitranshi, Anuptha Pujari, Vianessa Ng, Ashley Kubley, Ronald Hudepohl, V. Shanov, Devanathan Anantharaman, D. Chen, Devika Chauhan, M. Schulz
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引用次数: 4

摘要

设计了一种用于制造碳纳米管(CNT)织物和碳杂化材料(CHM)的反应器系统。在气相热解法中,碳纳米管在反应器管中形成网或短袜。所述袜子从反应器管中退出,并逐层缠绕在鼓上,以直接形成非织造布。金属纳米颗粒和连续微纤维可以整合到合成过程中形成CHM。织物的连续直接制造是该方法的一个优点。然而,在我们的特殊反应器系统中,这种制造过程的可靠性受到几个问题的影响。这些问题包括:套管偶尔会断裂,由于内部积碳而需要每天清洗陶瓷反应器管,反应器管下垂/弯曲,以及处理反应产生的氢气的安全性。对这些问题提出了可能的解决办法。这项研究的重要性在于,没有其他块状材料具有碳纳米管混杂织物的综合性能。如果纳米管的性能可以进一步改进和定制,如果这种材料的制造可以在合理的成本下扩大规模,那么纳米管定制材料的许多新的商业应用就可以打开。
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Reactor Design for Manufacturing Carbon Hybrid Materials
This paper addresses the design of a reactor system for manufacturing carbon nanotube (CNT) fabric and carbon hybrid materials (CHM). A web or sock of CNT is formed in a reactor tube in the gas phase pyrolysis method. The sock exits the reactor tube and is wound layer by layer onto a drum to directly form a nonwoven fabric. Metal nanoparticles and continuous microfibers can be integrated into the synthesis process to form CHM. Continuous direct manufacturing of fabric is an advantage of the method. However, the reliability of this manufacturing process in our particular reactor system is affected by several problems. These include occasional breaking of the sock, the need for daily cleaning of the ceramic reactor tube due to carbon deposits on the inside, sagging/bending of the reactor tube, and safety in handling the hydrogen gas produced from the reaction. Possible solutions to the problems are proposed. The importance of this research is that no other bulk material has the combination of properties of CNT hybrid fabric. If the properties can be further improved and customized, and if manufacturing of the material can be scaled-up at reasonable cost, many new commercial applications for nanotube custom materials could open up.
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