纳米银敏化掺铕磷酸盐玻璃光学与力学性能的相关性研究

Ibrahim Mohammed Danmalam, I. Bulus, S. K. Ghoshal, R. Ariffin
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引用次数: 0

摘要

采用熔淬法制备了63.5P2O5-20MgO -15ZnSO4-1.5Eu2O3 -yAgNps (y = 0.0、0.1、0.3、0.5、0.7、0.9和1.1 g)组成的不同浓度AgNPs镁锌硫磷酸钠玻璃。然后对淬火玻璃进行表征,建立光学和机械特性之间的关系。随着AgNPs嵌入水平的增加,密度从3.0720 g.cm-3增加到4.3304 g.cm-3,表明网络收缩,致密性增强。玻璃的杨氏模量、剪切模量和体积模量随AgNPs含量的增加而增加。泊松比由0.0978提高到0.1416,维氏硬度由0.0658提高到0。GPa从0.8350提高到0.8916。这就需要对合成玻璃的超声性能和力学性能进行评估,并通过各种分析工具进行进一步分析。所研究的玻璃可用于硬表面工程的发展。
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Correlation of Optical and Mechanical Properties of Silver Nanoparticles Sensitized Europium Doped Phosphate Glasses
Magnesium-zinc-sulfophosphate glasses with various concentration of Silver nanoparticles (AgNPs) compose of 63.5P2O5–20MgO –15ZnSO4–1.5Eu2O3 –yAgNps (y = 0.0, 0.1, 0.3, 0.5, 0.7,0.9 and 1.1 g in excess) were prepared via melt-quenching method.  As-Quenched glasses were then characterized to establish the relationship between optical and mechanical characteristics. Densities were found to increase from 3.0720 to 4.3304 g.cm-3 with increase in AgNPs embedding levels, suggesting the network shrinkages and enhanced compactness. The Young’s, shear and bulk modulus of glasses were observed to enhance with the increase in AgNPs contents. The Poisson’s ratio value increased from (0.0978 to 0.1416) while values of both Vickers hardness (from 0.0658 to 0. 0.0682 GPa) as well as  (from 0.8350 to 0.8916) were increased. This necessitate the evaluation of ultrasonic properties and mechanical properties of the synthesized glasses and further analysed by various analytical tools. The studied glass may be useful for the development of hard surface engineering.
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