苹果渣在水和污水中重金属去除中的应用

Kamila Gryko, M. Kalinowska, G. Świderski
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引用次数: 5

摘要

有毒物质在环境中的释放仍然是一个问题,尽管我们加大了减少这一问题的努力。常用的去除水和废水中重金属离子的方法存在效率低、成本高等缺点。由于重金属和染料在环境中的毒性和稳定性,它们是最有问题的污染物。因此,近年来,诸如天然材料吸附等修复技术得到了发展。然而,这些技术在工业层面上仍然很少使用。最近,科学家们试图将纳米技术的前景应用于这一领域,研究在纳米尺度上使用生物吸附剂处理废水的可能性。制备经济、高效、环保的吸附剂及其化学改性是提高水和废水中金属去除效率的重要途径。农业废料是廉价的吸附剂,几乎不需要处理。这种生物吸附剂不能去除特定的金属离子,但通过化学改性可以提高其吸附能力和特异性。来自文献的数据报告了各种类型的生物吸附材料,例如,水果或蔬菜渣和坚果壳。苹果渣是最有前途的原料之一。据估计,近年来,全球苹果产量达到约7500万吨,相当于每年500 - 700万吨苹果渣。这类废物的管理是一项严峻的挑战。对耗尽资源的合理管理需要从废物作为可重复使用的原材料的角度来看待废物。通过对苹果渣吸附重金属的参数(pH、吸附剂用量、动力学等)的研究,探讨了苹果渣对重金属的吸附潜力。
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The Use of Apple Pomace in Removing Heavy Metals from Water and Sewage
The release of toxic substances in the environment continues to be a problem despite increased efforts to reduce this. The commonly used methods of removing heavy metal ions from water and wastewater have many disadvantages, including a low efficiency and high cost. Heavy metals and dyes are the most problematic pollutants due to their toxicity and stability in the environment. For this reason, in recent years, remediation technologies such as the sorption on materials of natural origin, have been developed. However, these technologies are still rarely used at an industrial level. Recently, scientists have attempted to apply the promising properties of nanotechnology to this field, conducting research on the possibility of using biosorbents in the nanoscale in wastewater treatment. Much attention is currently paid to the preparation of cost-effective, efficient, and environmentally friendly adsorbents, as well as their chemical modifications, to increase the metal removal efficiency from water and wastewater. The waste materials from the agricultural industry are cheap adsorbents that require little treatment. This kind of biosorbent is not able to remove specific metal ions, but by chemical modifications its adsorption capacity and specificity can be increased. The data from the literature are reported for various types of bio-adsorbent materials, e.g., fruit or vegetable pomace and nut shells. One of the most promising raw materials is apple pomace. It was estimated that, in recent years, global apple production reached approximately 75 million tons, equating to 5–7 million tons of apple pomace per year. The management of such waste is a serious challenge. The rational management of exhausting resources requires looking at waste in terms of its use as a reusable raw material. The aim of this paper was to collect information and compare the parameters (pH, dose of adsorbent, and kinetics, etc.) of heavy metal sorption on apple pomace in order to demonstrate the potential of this adsorbent application.
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