基于 WC 的金属陶瓷 HVOF 涂层的热腐蚀、氧化和微观结构实验研究

IF 2.1 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Oxidation of Metals Pub Date : 2023-08-26 DOI:10.1007/s11085-023-10179-x
Naveen Kumar, Vikas Kumar Choubey
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引用次数: 0

摘要

316LSS 广泛应用于各种工业领域,包括热交换器、染色设备、纸浆和造纸设备,以及用于化工、染料、造纸、草酸、化肥等的船舶设备。在这些应用中,腐蚀一直是最严重的问题。因此,本研究具体介绍了 316LSS 的特点、使用抑制剂进行控制、奥氏体 316LSS 抑制剂效率研究、使用环境、浓度、实验分析,并强调了有机抑制剂对可持续发展工业的重要性。在 316LSS 上涂覆热稳定的 HVOF WC-10Co-4Cr 粉末涂层可以减少这种影响。本研究探讨了 HVOF 金属陶瓷粉末涂料对 316LSS 微观结构、氧化和腐蚀行为评估的影响,在 800 °C 的 Na2SO4-88%Fe2 (SO4)3恶劣环境中最多可进行 50 次。每个循环在 800 °C 下加热一小时,在环境温度下冷却二十分钟。使用热重法研究了热腐蚀动力学,发现这些动力学遵循抛物线速率规则。结果分析表明,316LSS 上喷涂的 HVOF 86WC-10Co-4Cr 涂层与未涂覆的基体金属相比,具有优异的抗氧化性和抗腐蚀性,并且在测试环境下涂层与基体具有良好的附着力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Experimental Investigation on Hot Corrosion, Oxidation and Microstructure of WC Based Cermet HVOF Coating

316LSS is used in various industrial applications, including heat exchangers, dyeing equipment, pulp and paper equipment, and marine equipment for chemicals, dyes, paper, oxalic acid, fertilizer, etc. Corrosion has always been the most serious problem across these applications. For this reason, this research specifies the features of 316LSS, the use of inhibitors for control, austenitic 316LSS research with inhibitor efficiency, the environment employed, its concentration, experimental analysis, and an emphasis on organic inhibitors for a sustainable industry. Applying thermally stable HVOF WC-10Co-4Cr powder coatings over the 316LSS can reduce this impact. The current study examines the effects of HVOF cermets powder coatings on the assessment of the 316L SS microstructure, oxidation, and corrosion behavior in a hostile situation of Na2SO4-88%Fe2 (SO4)3 at 800 °C for up to 50 times. Every cycle lasted one hour at 800 °C for heating and twenty minutes at ambient temperature for cooling. The thermogravimetric method was used to study the hot corrosion kinetics, and it was discovered that these abide by the parabolic rate rule. The analysis of the results identified that the HVOF 86WC-10Co-4Cr sprayed coating on 316LSS has shown excellent oxidation and resistance to corrosion as compared to uncoated base metal and good coating adherence to the substrate under the tested environment.

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来源期刊
Oxidation of Metals
Oxidation of Metals 工程技术-冶金工程
CiteScore
5.10
自引率
9.10%
发文量
47
审稿时长
2.2 months
期刊介绍: Oxidation of Metals is the premier source for the rapid dissemination of current research on all aspects of the science of gas-solid reactions at temperatures greater than about 400˚C, with primary focus on the high-temperature corrosion of bulk and coated systems. This authoritative bi-monthly publishes original scientific papers on kinetics, mechanisms, studies of scales from structural and morphological viewpoints, transport properties in scales, phase-boundary reactions, and much more. Articles may discuss both theoretical and experimental work related to gas-solid reactions at the surface or near-surface of a material exposed to elevated temperatures, including reactions with oxygen, nitrogen, sulfur, carbon and halogens. In addition, Oxidation of Metals publishes the results of frontier research concerned with deposit-induced attack. Review papers and short technical notes are encouraged.
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