{"title":"基于 WC 的金属陶瓷 HVOF 涂层的热腐蚀、氧化和微观结构实验研究","authors":"Naveen Kumar, Vikas Kumar Choubey","doi":"10.1007/s11085-023-10179-x","DOIUrl":null,"url":null,"abstract":"<div><p>316LSS is used in various industrial applications, including heat exchangers, dyeing equipment, pulp and paper equipment, and marine equipment for chemicals, dyes, paper, oxalic acid, fertilizer, etc. Corrosion has always been the most serious problem across these applications. For this reason, this research specifies the features of 316LSS, the use of inhibitors for control, austenitic 316LSS research with inhibitor efficiency, the environment employed, its concentration, experimental analysis, and an emphasis on organic inhibitors for a sustainable industry. Applying thermally stable HVOF WC-10Co-4Cr powder coatings over the 316LSS can reduce this impact. The current study examines the effects of HVOF cermets powder coatings on the assessment of the 316L SS microstructure, oxidation, and corrosion behavior in a hostile situation of Na<sub>2</sub>SO<sub>4</sub>-88%Fe<sub>2</sub> (SO<sub>4</sub>)<sub>3</sub> at 800 °C for up to 50 times. Every cycle lasted one hour at 800 °C for heating and twenty minutes at ambient temperature for cooling. The thermogravimetric method was used to study the hot corrosion kinetics, and it was discovered that these abide by the parabolic rate rule. The analysis of the results identified that the HVOF 86WC-10Co-4Cr sprayed coating on 316LSS has shown excellent oxidation and resistance to corrosion as compared to uncoated base metal and good coating adherence to the substrate under the tested environment.</p></div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 3","pages":"413 - 432"},"PeriodicalIF":2.1000,"publicationDate":"2023-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Experimental Investigation on Hot Corrosion, Oxidation and Microstructure of WC Based Cermet HVOF Coating\",\"authors\":\"Naveen Kumar, Vikas Kumar Choubey\",\"doi\":\"10.1007/s11085-023-10179-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>316LSS is used in various industrial applications, including heat exchangers, dyeing equipment, pulp and paper equipment, and marine equipment for chemicals, dyes, paper, oxalic acid, fertilizer, etc. Corrosion has always been the most serious problem across these applications. For this reason, this research specifies the features of 316LSS, the use of inhibitors for control, austenitic 316LSS research with inhibitor efficiency, the environment employed, its concentration, experimental analysis, and an emphasis on organic inhibitors for a sustainable industry. Applying thermally stable HVOF WC-10Co-4Cr powder coatings over the 316LSS can reduce this impact. The current study examines the effects of HVOF cermets powder coatings on the assessment of the 316L SS microstructure, oxidation, and corrosion behavior in a hostile situation of Na<sub>2</sub>SO<sub>4</sub>-88%Fe<sub>2</sub> (SO<sub>4</sub>)<sub>3</sub> at 800 °C for up to 50 times. Every cycle lasted one hour at 800 °C for heating and twenty minutes at ambient temperature for cooling. The thermogravimetric method was used to study the hot corrosion kinetics, and it was discovered that these abide by the parabolic rate rule. The analysis of the results identified that the HVOF 86WC-10Co-4Cr sprayed coating on 316LSS has shown excellent oxidation and resistance to corrosion as compared to uncoated base metal and good coating adherence to the substrate under the tested environment.</p></div>\",\"PeriodicalId\":724,\"journal\":{\"name\":\"Oxidation of Metals\",\"volume\":\"101 3\",\"pages\":\"413 - 432\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2023-08-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Oxidation of Metals\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11085-023-10179-x\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Oxidation of Metals","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11085-023-10179-x","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Experimental Investigation on Hot Corrosion, Oxidation and Microstructure of WC Based Cermet HVOF Coating
316LSS is used in various industrial applications, including heat exchangers, dyeing equipment, pulp and paper equipment, and marine equipment for chemicals, dyes, paper, oxalic acid, fertilizer, etc. Corrosion has always been the most serious problem across these applications. For this reason, this research specifies the features of 316LSS, the use of inhibitors for control, austenitic 316LSS research with inhibitor efficiency, the environment employed, its concentration, experimental analysis, and an emphasis on organic inhibitors for a sustainable industry. Applying thermally stable HVOF WC-10Co-4Cr powder coatings over the 316LSS can reduce this impact. The current study examines the effects of HVOF cermets powder coatings on the assessment of the 316L SS microstructure, oxidation, and corrosion behavior in a hostile situation of Na2SO4-88%Fe2 (SO4)3 at 800 °C for up to 50 times. Every cycle lasted one hour at 800 °C for heating and twenty minutes at ambient temperature for cooling. The thermogravimetric method was used to study the hot corrosion kinetics, and it was discovered that these abide by the parabolic rate rule. The analysis of the results identified that the HVOF 86WC-10Co-4Cr sprayed coating on 316LSS has shown excellent oxidation and resistance to corrosion as compared to uncoated base metal and good coating adherence to the substrate under the tested environment.
期刊介绍:
Oxidation of Metals is the premier source for the rapid dissemination of current research on all aspects of the science of gas-solid reactions at temperatures greater than about 400˚C, with primary focus on the high-temperature corrosion of bulk and coated systems. This authoritative bi-monthly publishes original scientific papers on kinetics, mechanisms, studies of scales from structural and morphological viewpoints, transport properties in scales, phase-boundary reactions, and much more. Articles may discuss both theoretical and experimental work related to gas-solid reactions at the surface or near-surface of a material exposed to elevated temperatures, including reactions with oxygen, nitrogen, sulfur, carbon and halogens. In addition, Oxidation of Metals publishes the results of frontier research concerned with deposit-induced attack. Review papers and short technical notes are encouraged.