用于增强化学酶催化的磁性皱褶有机硅基金属-酶集成催化剂

Yunting Liu , Na Guo , Weixi Kong , Shiqi Gao , Guanhua Liu , Liya Zhou , Jing Gao , Yanjun Jiang
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引用次数: 0

摘要

合成了核壳结构的磁性皱褶有机硅基金属-酶集成催化剂,并研究了它们在有机溶剂中手性胺的化学酶促动态动力学解析以及在水中手性醇的化学酶促合成中的催化性能。结构-性能研究表明,它们的可调结构和组成对化学合成催化过程中的活性、稳定性和可回收性的优化具有重要影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Magnetic wrinkled organosilica-based metal-enzyme integrated catalysts for enhanced chemoenzymatic catalysis

Core-shell structured magnetic wrinkled organosilica-based metal-enzyme integrated catalysts were synthesized, and their catalytic performances were studied in the chemoenzymatic dynamic kinetic resolution of chiral amines in an organic solvent, as well as in the chemoenzymatic synthesis of chiral alcohols in water. Structure-performance studies revealed the important influence of their tunable structure and composition on the optimization of activity, stability, and recyclability in chemoenzymatic catalysis.

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