聚(N,N′-二溴-N-乙基萘-2,7-二磺酰胺)作为合成2-芳基苯并咪唑和2-芳基-1-芳基甲基- 1h -1,3-苯并咪唑衍生物的高效试剂的合成、表征及应用

Vida Saleh, A. Khazaei, Hamid Abizadeh, Shahnaz Saednia
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引用次数: 1

摘要

以聚(N,N ' -二溴-N-乙基萘-2,7-二磺酰胺)(PBNS)为新型多相催化剂,在乙腈中进行了邻苯二胺(OPD)与芳基醛的缩合反应。PBNS具有过滤简单、制备简单、可回收性好、使用方便、在正常条件下稳定等优点,而且不具有分子溴的危险性。
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Synthesis, Characterization, and Application of Poly(N,N′-dibromo-N-ethylnaphthyl-2,7-disulfonamide) as an Efficient Reagent for the Synthesis of 2-Arylbenzimidazole and 2-Aryl-1-arylmethyl-1H-1,3-benzimidazole Derivatives
The condensation of O-phenylenediamine (OPD) with aryl aldehydes is carried out in acetonitrile using poly(N,N′-dibromo-N-ethylnaphthyl-2,7-disulfonamide) (PBNS) as a novel and heterogeneous catalyst. PBNS has some potential advantages which include ease of separation from the reaction mixture by simple filtration, easy preparation, recoverablility, convenience, and stability under normal condition and also is not dangerous as molecular bromine.
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