丝状藻干生物吸附剂对活性蓝52染料的生态吸附过程:平衡、动力学研究及干预效应

F. Mohammadi, Y. Rashtbari, Shirin Afshin, R. Askari, A. Moharrami, M. Vosoughi
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引用次数: 0

摘要

背景与目的:染料是一种结构复杂的材料,由于染色和印花过程中纺织废水的排放而进入环境。活性蓝52染料广泛用于纺织工业。因此,我们研究了丝状藻作为天然吸附剂对纺织废水中活性蓝52染料的去除效果。方法:本实验采用实验室规模进行。研究了吸附剂剂量、接触时间、pH和不同染料浓度对吸附过程效率的影响,最后确定了Langmuir和Freundlich等温线数据的拟合率以及拟一阶和拟二阶吸附动力学。对于数据的分析,使用线性回归和r平方。结果:在RB52浓度为50 mg/L时,增加吸附剂剂量至22 g/100 mL,可使去除率提高至58.04%。当浓度分别为10和25 mg/L时,将初始pH从3提高到11,吸附量从31.2%提高到8.41%。结果表明,随着接触时间的增加,去除率提高,随着初始染料浓度的增加,去除率降低。Langmuir等温线与实测数据吻合较好。拟二阶动力学模型与实验数据拟合较好。结论:丝状藻作为天然吸附剂的去色效果较好。
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Eco-friendly Biosorption Process of Reactive Blue 52 Dye Using Alga Dried Biosorbent of Filamentous Alga Species: Equilibrium, Kinetic Studies and Intervening Effect
Background & objectives : Dyes are structurally complex materials, which enter into the environment due to discharging of textiles effluent from dyeing and printing processes. Reactive Blue 52 dye is used widely in the textile industry. Therefore, we investigated the efficiency of the filamentous Alga as natural adsorbent in the removal of Reactive Blue 52 dye from textile wastewater. Methods: This experimental study was performed in laboratory scale. In this study, the effect of adsorbent dose, contact time, pH and different dye concentrations on efficiency of adsorption process were studied and finally, fitting rate of data for Langmuir and Freundlich isotherms and also pseudo-first-order and pseudo-second-order adsorption kinetics were determined. For analysis of the data, linear regression and R-squared were used. Results: According to the obtained results, increasing of adsorbent dose to 22 g/100 mL in concentrations of 50 mg/L RB52 led to an increase of removal efficiency to 58.04%. Adsorption capacity was increased from 31.2 to 8.41 %, by increasing the initial pH from 3 to 11 for concentrations of 10 and 25 mg/L, respectively. Results showed that with the increase of contact time, removal efficiency increased and with increasing of initial dye concentration, the removal efficiency decreased. Langmuir isotherm was in good concordance with the data. The model of pseudo-second-order kinetic demonstrated better fitting with the experimental data. Conclusion: The results indicated the suitability of filamentous Alga as natural adsorbent for color removal.
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