用阳极溶出伏安法测定拉各斯市地下水、地表水和自来水中的重金属

O. Ehi-EromoseleC., O. OkieiW.
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引用次数: 32

摘要

采用差分脉冲阳极溶出伏安法(DPASV)测定了拉各斯市部分地区地表水、地下水和自来水中的重金属污染水平。对这些样品的铅、铜和镉含量进行了分析,并与世卫组织(2008年)规定的饮用水污染物水平进行了比较。结果表明,所调查的井水和钻孔水样均含有高浓度的重金属。铅和镉的浓度高于世界卫生组织的最大可接受浓度(MAC)。然而,没有一个样品的铜浓度超过世卫组织铜的MAC标准。在整个分析样本中,只有从奥霍塔州的Odo-Iyaalaro河采集的样本没有显示铅污染。其他样本显示所有被分析的金属都受到了污染。总的来说,考虑到这些金属的毒性,而且大多数情况下,当所研究的水源是大量人口的主要水源时,结果显示出污染危害的迹象。发现所调查样品的DPASV结果与原子吸收光谱独立工作获得的相同样品的结果相当。
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Heavy Metal Assessment of Ground, Surface and Tap Water Samples in Lagos Metropolis Using Anodic Stripping Voltammetry
The levels of heavy metal contamination in surface, ground and tap waters collected in some part of Lagos metropolis were determined using Differential Pulse Anodic Stripping Voltammetry (DPASV). The samples were analysed for their contents of lead, copper and cadmium and were also compared with the WHO (2008) specified contaminant levels for drinking water. The results obtained showed that all the well water and borehole water samples investigated contain high concentration of these heavy metals. Lead and cadmium concentrations were found to be above the WHO maximum ac- ceptable concentration (MAC). However, none of the samples had copper concentration above the WHO MAC for copper. On the whole samples analysed, only the sample collected from Odo-Iyaalaro stream, Ojota showed no pollution of lead. Other samples showed pollution of all of the metals analysed. In general, the results show an indication of pollution hazards given the toxicity of these metals and mostly when the water sources studied represent the major sources of water for the teeming populace. DPASV results of the samples investigated were found to be comparable with results of same samples obtained from independent work carried out by Atomic Absorption Spectroscopy.
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