与玻璃增强环氧树脂衬里兼容的增产处理设计

Anastasia Bird, J. Espinoza-Perez, Karthik Mahadev, John Sixt
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摘要

玻璃增强环氧树脂(GRE)衬里是一种高分子复合材料,其主要成分是热固性树脂和玻璃纤维增强材料。其组成部分的综合性能导致材料具有优异的化学,热和机械性能。GRE衬板通常用于油井生产管的涂层,以保护管的冶金不受腐蚀环境的影响,从而延长管的使用寿命,节约成本。GRE衬套与许多用于增产作业的酸具有化学相容性,可提高产能。典型的酸,如盐酸、甲酸、乙酸等,涉及碳酸盐的去除,然后使用氢氟酸(HF)基酸去除小的地层颗粒。然而,由于与HF的潜在相互作用,通常不推荐在GRE衬管中使用HF。然而,在大多数砂岩储层中,由于消除了与细粒和粘土有关的地层损害,HF流体对恢复油井产能做出了巨大贡献。虽然GRE衬里是一种众所周知的技术,但由于其多相性,其与酸的化学相容性很难预测,并且需要专门的测试来了解其机械降解的可能性。BP之前的研究主要集中于在77°F的环境边界条件下,用9% HCl: 1% HF持续24小时评估GRE性能。这些测试对GRE造成了不可接受的机械退化,因此放弃了对GRE内衬井进行增产处理的计划。然而,越来越多的GRE衬套性能不佳的注水井需要采用含0.5% HF的弱酸性设计。因此,在120°F和140°F的高温下,在长达72小时的时间内,研究人员评估了0.5% HF在特定井界条件下GRE衬管的相容性、机械和物理性质的变化。此外,还进行了岩心流动测试,以评估GRE暴露酸对地层潜在损害的影响。该研究表明,将GRE衬套暴露在0.5% HF环境中,可以保持良好的机械性能,并且不会对地层造成任何损害。这些结果也反映在现场表现中,注入能力指数显著提高到>4,从而为多个地区的GRE衬管井数量的显著增加打开了大门。
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Stimulation Treatment Design Compatible with Glass Reinforced Epoxy Lining
Glass reinforced epoxy (GRE) lining is a polymer composite material, the main components of which are a thermosetting resin and a fiberglass reinforcement. The combined properties of its components result in a material with excellent chemical, thermal and mechanical performance. GRE lining is typically used as a coating on production tubulars in oil wells to protect metallurgy of tubulars from corrosive environments, thereby extending the life of tubulars and realizing cost savings. GRE lining is chemically compatible with many acids used in well stimulation to restore productivity. Typical acids such as hydrochloric, formic, acetic etc. involve carbonate removal followed using hydrofluoric (HF) based acids for removal of small formation particles. However, the use of HF is typically not recommended in GRE lined tubulars due to potential interactions with HF. Yet, in most sandstone reservoirs, HF fluids contribute greatly to restoring well productivity due to formation damage removal related to fines and clays. While GRE lining is a well-known technology, its chemical compatibility with acids is challenging to predict due to its heterogenous nature and requires specific testing to understand potential for mechanical degradation. Prior studies at BP focused on evaluation of GRE performance with 9% HCl: 1% HF under ambient boundary conditions of 77°F for 24 hours. These tests caused unacceptable levels of mechanical degradation to GRE and plans to execute stimulation treatments in GRE lined wells were abandoned. However, an increasing number of GRE lined underperforming water injector well stock necessitated a less aggressive acid design involving 0.5% HF. Therefore, 0.5% HF was assessed for GRE lining compatibility, mechanical and physical property changes under specific well boundary conditions at elevated temperatures of 120°F and 140°F and extended times of up to 72 hours. Core flow tests were also carried out to evaluate the effect of GRE exposed acid to any potential for formation damage. This study demonstrated that exposure of GRE lining to 0.5% HF resulted in acceptable retention of mechanical properties and did not show any formation damage impacts. These results were also reflected in field performance where a significant injectivity index improvement of >4 was achieved, thereby opening the door to a significant increase in number of GRE lined wells to be treated across multiple regions.
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