Ho取代Bi0.90La0.10FeO3多铁材料的晶体结构、磁性能和介电性能研究

Jogender Singh, A. Agarwal, S. Sanghi, M. Yadav, Tanvi Bhasin, U. Bhakar
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引用次数: 0

摘要

研究了固相反应法制备的多晶Bi0.90-xLa0.10HoxFeO3(0.15& 0.15,分别标记为LH15和LH20)的结构行为、磁测量和介电特性的变化。粉末x射线衍射和XRD谱的Rietveld细化表明,bi0.90 la0.10 feo3多铁材料在R3c中具有单相。XRD的Rietveld精细化谱分析表明,样品LH15在a位的钬取代结晶为菱形R3c和正交pham空间基的组合。钬取代LH20使Bi0.90La0.10FeO3的菱形R3c对称转变为正交Pbam对称。通过记录磁化率为±6kOe来研究其磁性行为。所有样品的弱铁磁行为表明共掺杂通过改变倾斜角度有效地掩盖了螺旋自旋构型。用阻抗分析仪在100Hz ~ 7MHz频率范围内测量了制备的陶瓷化合物在不同温度下的介电行为。研究了固相反应法制备的多晶Bi0.90-xLa0.10HoxFeO3(0.15& 0.15,分别标记为LH15和LH20)的结构行为、磁测量和介电特性的变化。粉末x射线衍射和XRD谱的Rietveld细化表明,bi0.90 la0.10 feo3多铁材料在R3c中具有单相。XRD的Rietveld精细化谱分析表明,样品LH15在a位的钬取代结晶为菱形R3c和正交pham空间基的组合。钬取代LH20使Bi0.90La0.10FeO3的菱形R3c对称转变为正交Pbam对称。通过记录磁化率为±6kOe来研究其磁性行为。所有样品的弱铁磁行为表明共掺杂通过改变倾斜角度有效地掩盖了螺旋自旋构型。研究了制备的陶瓷化合物的介电性能。
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Investigation of the crystal structure, magnetic properties and dielectric properties of Ho substituted Bi0.90La0.10FeO3 multiferroics
The change in structural behaviour, magnetic measurement & dielectric characteristics of polycrystalline Bi0.90-xLa0.10HoxFeO3(0.15& 0.15) and labelled as LH15 and LH20 respectively) which were prepared using method of the solid-state reaction, have been investigated. The powder X-ray diffraction and Rietveld refinement of the XRD spectrum indicates that Bi0.90La0.10FeO3multiferroics have single phase in R3c. Rietveld refined spectrum of the XRD conclude that holmium substitution at A-site for the samples LH15 is crystallized as combo of rhombohedral R3c and orthorhombic Pbam space group. Holmium substitution for LH20 has changed the rhombohedral R3c symmetry of Bi0.90La0.10FeO3 to the orthorhombic Pbam symmetry. The magnetic behaviour was studied by recording magnetization with magnetic up to ±6kOe. Weak ferromagnetic behaviour of all samples attributes that co-doping effectively concealed spiral spin configuration by altering the canting angle. Dielectric behaviour of prepared ceramic compounds was carried by impedance analyser within frequency ranged 100Hz - 7MHz for different temperatures.The change in structural behaviour, magnetic measurement & dielectric characteristics of polycrystalline Bi0.90-xLa0.10HoxFeO3(0.15& 0.15) and labelled as LH15 and LH20 respectively) which were prepared using method of the solid-state reaction, have been investigated. The powder X-ray diffraction and Rietveld refinement of the XRD spectrum indicates that Bi0.90La0.10FeO3multiferroics have single phase in R3c. Rietveld refined spectrum of the XRD conclude that holmium substitution at A-site for the samples LH15 is crystallized as combo of rhombohedral R3c and orthorhombic Pbam space group. Holmium substitution for LH20 has changed the rhombohedral R3c symmetry of Bi0.90La0.10FeO3 to the orthorhombic Pbam symmetry. The magnetic behaviour was studied by recording magnetization with magnetic up to ±6kOe. Weak ferromagnetic behaviour of all samples attributes that co-doping effectively concealed spiral spin configuration by altering the canting angle. Dielectric behaviour of prepared ceramic compounds was carr...
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