纳米晶体多孔薄膜储氢技术

A. Guglya, E. Lyubchenko
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摘要

提交稿件| http://medcraveonline.com作为固态氢存储。V-H体系包括:α固溶体;β-(vh0.45 - vh0.95)为体心四边形晶格(bct), γ-VH2为fcc晶格。Ti-H体系也有三个相:α-固溶体;β-(tih0.5 ~ tih0.9)为bcc晶格,δ - TiH2为fcc晶格。γ-VH2中储存氢的总质量接近2.1 wt.%。δ -TiH2吸收4.0 wt.% H2。因此,在VH2中吸收氢原子的量为11.2,在TiH2中为9.1 (at/cm3, x1022)。为了满足美国能源部(DOE)的要求[1](重量电容:>5.4wt%;氢气释放温度范围:< 85℃:达到最大氢气通量所需的时间周期:4秒;平衡压力:< 0.4 MPa),需要解决几个具有挑战性的问题:
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Nano Crystalline Porous Thin Film Hydrogen Storages
Submit Manuscript | http://medcraveonline.com as solid state hydrogen storages. V-H system includes the following phases: αsolid solution; β-(VH0.45VH0.95) with bodycentered tetragonal lattice (bct) and γ-VH2 with fcc lattice. There are three phases in Ti-H system also: α-solid solution; β-(TiH0.5-TiH0.9) with bcc-lattice and δ – TiH2 with fcc-lattice. The total mass of stored hydrogen in γ-VH2 approaches value of 2.1 wt.%. δ -TiH2 absorbs 4.0 wt.% H2. Therefore, the amount of absorbed hydrogen atoms comes to be 11.2 in VH2 is and 9.1 in TiH2 (at/cm3, x1022). In order to meet the U.S. Department of Energy (DOE) requirements [1] (gravimetric capacitance: >5.4wt%; hydrogen release temperature range: < 85°C: the time period required to achieve the maximum hydrogen flux: 4 seconds; the equilibrium pressure: < 0.4 MPa), it is necessary to solve several challenging problems:
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