TiO2和Pd/TiO2作为酮类加氢光催化剂及其膜应用前景

C. Lavorato, P. Argurio, Samir M. EL-Medania, R. Molinari
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引用次数: 5

摘要

在目前应用于工业实践的主要化学转化中,还原过程,如相应醇中羰基化合物的还原,在有机合成中起着重要作用[1-3]。特别是,苯乙酮(AP)加氢已被广泛研究,因为所得到的还原产物1-苯乙醇或苯基乙醇(PE)是制备镇痛和抗炎药物以及香料和香水的常见前体[4-6]。
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TiO2 and Pd/TiO2 as Photocatalysts for Hydrogenation of Ketones and Perspective of Membrane Application
Among the main chemical transformations, currently applied in industrial practices, reduction processes, such as the reduction of carbonyl compounds in the corresponding alcohols, play an important role in organic synthesis [1-3]. In particular, acetophenone (AP) hydrogenation has been widely studied since the resultant reduction product, 1-phenylethyl alcohol or also phenyl ethanol (PE), is a common precursor for the preparation of analgesic and anti-inflammatory drugs as well as fragrances and perfumes [4-6].
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