燃烧溶胶-凝胶法制备过渡金属铁氧体(Co, Cu, Ni, Mn)及微波处理

S. Zulfugarova, G. Azimova, Z. Aleskerova, Y. Litvishkov, D. Tagiyev
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引用次数: 1

摘要

本文综述了近年来溶胶-凝胶法合成过渡金属铁氧体(Co, Cu, Ni, Mn)的研究进展以及微波辐射的影响。铁氧体不仅具有磁性和光学性质,而且具有催化性质。近年来,越来越多的文献研究了过渡金属铁氧体在包括氧化反应在内的各种反应中的催化性能。鉴于在溶胶-凝胶法中,各种有机组分被用作络合剂和燃料,本文考虑了有机试剂的性质、与前驱体的比例、介质的pH、微波照射的功率和时间等因素对铁氧体形成过程中形成颗粒的大小和结构特征的影响,这些因素在催化过程中具有重要意义。近年来,物理场(包括微波场)对包括纳米催化剂合成在内的各种化学过程的影响的研究引起了催化领域化学家的关注。利用微波辐射在溶胶-凝胶法合成铁氧体中可以获得具有高比表面积的纳米铁氧体。从这个角度出发,本文综述了近年来致力于微波溶胶-凝胶合成铁氧体的研究工作。
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Synthesis of Transition Metal Ferrites (Co, Cu, Ni, Mn) by the Sol-Gel Method with Combustion and the Use of Microwave Processing
This review considers recent work on the synthesis of transition metal ferrites (Co, Cu, Ni, Mn) by sol-gel method with combustion, as well as the effect of microwave radiation. Ferrites are interesting not only for magnetic and optical properties, but also for their catalytic properties. In recent years, there has been an in-creasing amount of literature, which investigates the catalytic properties of transition metal ferrites in various reactions, including oxidative reactions. Given the fact that various organic components are used as complex-ing agents and as a fuel in the sol-gel method with combustion, the review considers the influence of the or-ganic reagent nature, its ratio to precursors, the pH of the medium, the power and time of microwave expo-sure to the process of ferrite formation as factors influencing the size of formed particles and their textural characteristics, which are of great importance in the catalysis. Recently, the attention of chemists working in the field of catalysis has been attracted by studies of the effect of physical fields, to which the microwave field belongs, on various chemical processes, including the nanocatalysts synthesis. The use of microwave ra-diation in sol-gel synthesis of ferrite allows obtaining nanoferrites with high specific surface area. From this point of view, this paper considers the works of recent years devoted to the study of microwave sol-gel syn-thesis of ferrite.
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