碱性浓度和养护温度对粉煤灰地聚合物砂浆耐久性的影响

Abel Woldu Ourgessa, Aseged Tebeje Tasew, Rahel Alemu Hafa
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摘要

本研究以粉煤灰为原料,用不同浓度的NaOH和高粘性的na -硅酸盐配制成活化溶液,合成地聚合物砂浆。制备的NaOH浓度分别为8M、12M和14M。制备的地聚合物在不同温度(环境温度、40℃和60℃)下固化,并通过加速耐久性试验来确定其强度、粘结结构、机械性能以及在酸性和咸味环境下的耐受性。FTIR结果显示铝硅酸盐键结构有明显的峰。在室温下固化14M样品达到最大强度。碱度越高,抗压和抗折强度越高,吸水率越低。在较高温度和较高摩尔浓度下固化的样品具有较低的吸水能力和较高的抗极端环境能力。常温固化8M,暴露于酸性环境中,最大质量损失为10.9%。
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The Effect of Alkaline Concentration and Curing Temperature on the Durability of Fly Ash Geopolymer Mortar
In this study, fly ash was used to synthesize geopolymer mortar by using an activating solution prepared from a different concentration of NaOH and a highly viscous Na-silicate. The NaOH concentration prepared were 8M, 12M, and 14M. The prepared geopolymers were cured at different temperatures (ambient, 40°C, and 60°C) and were studied to determine their strength, bond structure, mechanical properties, and resistance in an acidic and salty environment using an accelerated durability test. FTIR results showed distinctive peaks of aluminosilicate bond structures. Maximum strength was achieved for 14M samples cured at room temperature. Higher alkalinity resulted in higher compressive and flexural strength and lower water absorption. Lower water absorption capacity and higher resistance to the extreme environment were achieved for samples cured at higher temperatures and higher molarities. The maximum mass loss was 10.9% for 8M cured at ambient temperature exposed to an acidic environment.
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