不同化学添加剂对硫酸钙水垢的溶解效果

Faisal M. Alissa, Norah W. Aljuryyed, Salem A. Balharth, M. Leoni
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引用次数: 5

摘要

硫酸钙结垢是油田行业生产稳定性面临的挑战之一,也是最难管理的结垢之一。硫酸盐垢由于其溶解度低而很难溶解。研究了不同化学添加剂和配方对硫酸钙水垢的溶解性能。本研究将研究各种化学添加剂和配方的最大溶出量(克水垢/摩尔螯合剂),以评价其对硫酸钙水垢的溶出效率。在多种剂量、pH值和催化剂的存在下进行了几个实验。以碳酸钾为催化剂,对硫酸钙水垢进行了溶解。研究了各种添加剂在催化和非催化途径下的性能。一系列的实验表明,添加剂用量、pH、催化剂等参数对溶解效率都有影响。通过对各添加剂(乳酸、柠檬酸、l -谷氨酸- n、n -二乙酸(GLDA)和葡萄糖酸)的溶出性能效率进行比较,确定了各添加剂在催化途径下的溶出效率。这项工作的结果将通过找到最有效、最便宜的方法来去除井筒中的硫酸钙垢,从而有助于增加经济价值。
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Calcium Sulfate Scale Dissolution Efficiency by Various Chemicals Additives
Calcium sulfate scale is one of the challenges that face production stability in the oilfield industry as it is one of the most challenging scales to manage. Sulfate-scales are very hard to dissolve because of their low solubility-product. This work studies the dissolution capacity of different chemical additives and recipes on calcium sulfate scales. In this work, the maximum dissolution capacity (gram of scale/mole of chelating agent) of various chemical additives and recipes will be studied to evaluate the efficiency in the dissolution of Calcium Sulfate scales. Several experiments were conducted at multiple doses, pH, and in-presence of a catalyst. Potassium Carbonate was used as a catalyst in the dissolution of Calcium Sulfate scales. The performance of each additive was studied in a catalyzed and non-catalyzed pathway and with various. A Series of experiments conducted showed that parameters such as the additive-dose, pH, and a catalyst affect the dissolution efficiency. The dissolution performance efficiency of each additive (Lactic Acid, Citric Acid, L-Glutamic Acid-N, N-diacetic Acid (GLDA), and Gluconic Acid) was compared to the additive performance efficiency under a catalyzed pathway in a formulated recipe. The outcome of this work will contribute to the economic value added by finding the most efficient and cheap recipe to remove Calcium Sulfate scales from the wellbore.
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