从物质的分子能量解包的物理模型出发,解释物质的熔化、沸腾、蒸发过程

G. G. Khaidarov
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摘要

本文在物质解包的分子能量模型的基础上,对物质的熔化、沸腾和蒸发过程提出了统一的能量方法。在此模型的基础上,发现了物质的熔点、沸点和临界点之间的能量变化关系。给出了这些温度与熔合潜热、内能、汽化焓的理论关系。将相关结果导出计算公式。所得公式由参考书数据和已知的经验依赖关系证实。这样,借助物质解包模型,又一次证实了表面张力现象与表面熔化、体积熔化、表面沸腾、体积沸腾和蒸发过程之间的统一联系
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EXPLANATION OF THE PROCESSES OF MELTING, BOILING, EVAPORATION OF A SUBSTANCE FROM THE PHYSICAL MODEL OF THE MOLECULAR-ENERGY UNPACKING OF A SUBSTANCE
In the article, based on the molecular energy model of unpacking of a substance, a unified energy approach to the processes of melting, boiling and evaporation of a substance is considered. Based on such a model, the relationship between the melting point, boiling point and critical point for a substance was found in terms of energy change. The theoretical correlation of each of those temperatures with the latent heat of fusion, internal energy, enthalpy of vaporization was shown. The results of the correlation were brought up to calculation formulas. The obtained formulas were confirmed by data from reference books and known empirical dependencies. Thus, with the help of the substance unpacking model, one more confirmation of the unified connection between the phenomenon of surface tension, processes of surface melting, melting in volume, surface boiling, boiling in volume, and evaporation was found
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