“son过氧化物”法氧化降解甲基橙

Y. Sukhatskyi, M. Shepida, Z. Znak
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摘要

研究了高级氧化法去除废水中甲基橙单偶氮染料的效果。针对甲基橙的强化氧化降解,提出了超声空化与“过氧化物”工艺-“son过氧化物”工艺相结合的方法。建立了甲基橙在初始浓度为25 mg/dm3(76.5·10-6 mol/dm3)的水溶液中氧化降解的合理条件:甲基橙:过氧化氢:偏碘酸钾的摩尔比= 1:50:10;反应介质pH - 3;温度- 293 K;空化超声处理比功率- 68 W/dm3。在此条件下,1800 s甲基橙的降解率达到89.4%。
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THE “SONOPEROXATE” PROCESS FOR OXIDATIVE DEGRADATION OF METHYL ORANGE
The efficiency of application of advanced oxidation processes for removal of methyl orange mono azo dye from wastewater is considered. For intensive oxidative degradation of methyl orange, it was proposed to use a combination of ultrasonic cavitation and “Peroxate” process – the “Sonoperoxate” process. Rational conditions for oxidative degradation of methyl orange at its initial concentration in an aqueous solution of 25 mg/dm3 (76.5·10-6 mol/dm3) were established: the molar ratio of methyl orange:hydrogen pero- xide:potassium metaperiodate = 1:50:10; pH of the reaction medium – 3; temperature – 293 K; specific power of cavitation ultrasonic treatment – 68 W/dm3. Under such conditions, the degradation degree of methyl orange of 89.4 % was achieved for 1800 s.
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SEARCHING OF BIOLOGICAL ACTIVITY OF S-ESTERS 4-ACETYLAMINOBENZENETHIOSULFOACID USING METHODS OF CHEMOINFORMATICS EPOXIDATION OF 1-OCTENE BY TERT-BUTYL HYDROPEROXIDE IN THE PRESENCE OF TITANIUM COMPOUNDS KINETICS OF DRYING OF MATCH SPLINTS HYDROGEL MEMBRANES BASED ON COPOLYMERS OF 2-HYDROXYETHYL METHACRYLATE WITH POLYVINYLPYRROLIDONE, MODIFIED WITH MONTMORILLONITE AND SILVER NANOPARTICLES ACOUSTIC CAVITATION NUMBER AND ITS EFFECT ON THE INTENSITY OF OXIDATIVE DEGRADATION OF CONGO RED DIAZO DYE
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