电介质三元化合物BNT-BKT-BT的规格

Israa M. Jamal, Emad K. Al-Shakarchi
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摘要

采用固相反应法制备了0.855(Bi0.5Na0.5TiO3) 0.115(Bi0.5K0.5TiO3)-0.03(BaTiO3)三元陶瓷化合物(BNT-BKT-BT)。采用三种不同的煅烧工艺作为温度和时间的函数,作为结构相的候选物。晶体结构分析证实了在致形相边界(MPB)内的衍射峰为菱形和四方相。在不同频率(1、10、100 kHz和3 MHz)和温度下的介电行为表明,在频率(100 kHz)范围内,最高居里温度为295℃。XRD分析表明,在(2)、(40)和(46)附近出现了峰分裂,这与不同相所提到的许多峰之间的重叠有关。弛豫剂铁电行为的出现强调了XRD分析和介电测量的一致性
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The Specification of Dielectric Ternary Compound BNT-BKT-BT
The ternary ceramic compound (BNT-BKT-BT), like 0.855(Bi0.5Na0.5TiO3) 0.115(Bi0.5K0.5TiO3)-0.03(BaTiO3) was prepared by solid-state reaction. Three different calcination processes as a function of temperature and time had been used as the candidate for the structural phase. The crystal structure analysis confirmed a rhombohedral and tetragonal phase regarding diffracted peaks within the morphotropic phase boundary (MPB). The dielectric behavior at different frequencies (1, 10, 100 kHz, and 3 MHz) and temperatures showed a maximum curie temperature at (295 C) through a frequency (100 kHz). The XRD analyses showed the peak splitting observed around (2=40, and 46) related to the overlapping between many peaks mentioned by different phases. The appearance of the relaxer ferroelectric behavior emphasizes the agreement of the XRD analysis and dielectric measurement
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