二氧化氮气敏层状WS2膜的单步CVD合成

Aanchal Alagh, F. Annanouch, E. Llobet
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引用次数: 2

摘要

最近,类似石墨烯的层状无机材料,如二维过渡金属二硫族化物(2D TMDs),已成为气敏行业的重要组成部分。事实上,它们表现出令人印象深刻的半导体特性、可调带隙、大表面积和优异的气体吸附能力。本文首次报道了利用无氢常压CVD技术,直接在氧化硅衬底上一步合成了层状WS2传感材料的三维组装,用于NO2电阻气体传感应用。利用E-SEM、EDX和拉曼光谱研究了生长材料的形貌和组成。对污染最严重的气体之一NO2的WS2传感器的演示显示出高灵敏度和低于20 ppb的低检测限的良好结果。
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Single-step CVD synthesis of layered WS2 films for NO2 gas sensing
Recently layered inorganic materials analogues to graphene such as two-dimensional transition metal dichalcogenides (2D TMDs) have emerged as promising building blocks for the gas sensing industry. Indeed, they show impressive semiconducting properties, tunable band gap, large surface area and excellent gas adsorbing capacities. Herein, we report for the first time, on a single step synthesis of 3D assembly of layered WS2 sensing material, via hydrogen free, atmospheric pressure CVD technique, directly on silicon oxide substrate for NO2 resistive gas sensing application. E-SEM, EDX and Raman spectroscopy were used to investigate the morphology and composition of the grown material. Demonstration of WS2 sensor towards one of the most pollutant gases (NO2) showed promising results with high sensitivity and low detection limit below 20 ppb.
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