{"title":"手性Cu(II)-Schiff碱配合物的制备及其在不对称催化中的应用","authors":"Leman Alkan","doi":"10.7212/ZKUFBD.V8I1.921","DOIUrl":null,"url":null,"abstract":"A chiral copper(II)-Schiff base complex was synthesized from L-Phenylalanine for the enantioselective Henry reaction. A variety of chiral β-nitroalcohols were obtained in good yield (up to 76%) with high enantioselectivities (up to 90% ee) under the optimized reaction conditions.","PeriodicalId":17742,"journal":{"name":"Karaelmas Science and Engineering Journal","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2018-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation Of A Chiral Cu(II)-Schiff Base Complex And Application For Asymmetric Catalysis\",\"authors\":\"Leman Alkan\",\"doi\":\"10.7212/ZKUFBD.V8I1.921\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A chiral copper(II)-Schiff base complex was synthesized from L-Phenylalanine for the enantioselective Henry reaction. A variety of chiral β-nitroalcohols were obtained in good yield (up to 76%) with high enantioselectivities (up to 90% ee) under the optimized reaction conditions.\",\"PeriodicalId\":17742,\"journal\":{\"name\":\"Karaelmas Science and Engineering Journal\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-06-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Karaelmas Science and Engineering Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.7212/ZKUFBD.V8I1.921\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Karaelmas Science and Engineering Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.7212/ZKUFBD.V8I1.921","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Preparation Of A Chiral Cu(II)-Schiff Base Complex And Application For Asymmetric Catalysis
A chiral copper(II)-Schiff base complex was synthesized from L-Phenylalanine for the enantioselective Henry reaction. A variety of chiral β-nitroalcohols were obtained in good yield (up to 76%) with high enantioselectivities (up to 90% ee) under the optimized reaction conditions.
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