利用农业固体废弃物制备的活性炭去除三环甲烷

El-Demerdash Fm, A. Am, I. Da
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引用次数: 7

摘要

一些饮用水厂使用高剂量氯来克服处理中的缺陷,至少确保向人口供应微生物安全的水。这一事实以及由于降雨增加和人为活动导致的水生资源中天然有机质(NOM)的增加正成为一个关键问题,因为氯化的副产品如三卤甲烷(THM)的形成是致癌物质。埃及饮用水系统采用新的处理方法对于满足质量准则至关重要。三卤甲烷是饮用水中存在的消毒副产物。在本研究中,采用吸附法去除供水系统中的THMs。考察了pH、接触时间、吸附剂和吸附剂浓度对吸附体系的影响。采用Langmuir和Freundlich吸附等温线模型对所得吸附数据进行分析。发现THM去除动力学遵循伪二阶模型,而不是Langmuir-Hinshelwood伪一阶模型。
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Removal of Trihalo Methanes Using Activated Carbon Prepared from Agricultural Solid Wastes
High chlorine dosages are used in some drinking water plants to overcome the deficiencies in the treatment to at least ensure a supply of microbiologically safe water to the population. This fact and the increment of natural organic matter (NOM) in the aquatic resources due to rainfall increases and anthropogenic activities are becoming a critical concern, due to the formation of chlorination by-products such as trihalomethanes (THM), which are carcinogenic substances. Egypt drinking water system using new treatments is essential to meet the quality guidelines. Trihalomethanes are carcinogenic by-products of disinfection that are present in drinking water. In the present research, adsorption was employed for the removal of THMs found in water supply systems. The effects of pH, contact time, adsorbents and adsorbate concentration on the adsorption system were investigated. The Langmuir and Freundlich adsorption isotherm models were used to analyse the resulting adsorption data. The kinetics of THM removal was found to follow the pseudo-second-order model rather than the Langmuir–Hinshelwood pseudo-first-order model.
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