巴西乌鲁库姆尾矿坝材料制备锰块的预还原研究

L. G. M. De Jesus, M. Tangstad
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摘要

在巴西,尾矿坝的废物处理一直是一个重大问题。在铁合金原料的生产过程中,由于其粒度小,从矿山中提取的材料中有多达50%被放置在尾矿坝中。这项工作的目的是评估用巴西乌鲁库姆尾矿坝材料制成的压块在锰铁合金生产过程中埋弧炉预还原区的性能。为了实现这项工作的目标,用两种不同的粘合剂制成的型煤在与预还原区相似的环境中进行了加热速率和大气成分的测试。此外,将成型煤与相同材料的块状煤进行了比较。除了预还原试验外,还对原材料和产品的孔隙率和抗压强度进行了评估。结果表明,该团聚体具有较好的综合性能。以糖蜜为粘结剂的成型煤具有较好的CO反应性。材料的抗压强度对焦炭的存在很敏感。以膨润土为粘结剂制备的团聚体经预还原后抗压强度较高。压块也比块状更容易腐烂。
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Prereduction of Manganese Briquettes Produced with Tailing Dam Materials from Urucum/Brazil
In Brazil, the waste disposal in tailing dams has been a significant problem. During the production of ferroalloy raw materials up to 50 % of the material extracted from the mines is placed in tailing dams due to its low particle size. The aim of this work is to evaluate the behaviour of briquettes made with tailing dam material from Urucum/Brazil in the prereduction zone of submerged arc furnaces during manganese ferroalloys production. To achieve the goals of the work, briquettes made with two different binders were tested in a similar environment to the pre-reduction zone, regarding heating rate and atmosphere composition. Furthermore, the briquettes were compared with lumps of the same material. Beside the prereduction tests, porosity and compressive strength of raw materials and products were also assessed. The results showed that the agglomerates had a better overall performance. The briquettes presented better CO reactivity, especially when molasses was used as binder. The compressive strength of the materials was sensitive to the presence of coke. Agglomerates made with bentonite as binder presented the higher compressive strength after prereduction. The briquettes also showed higher decrepitation than lumps.
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