叶片提取物对铝合金在碱性溶液中的腐蚀控制

L. Nnanna, I. Anozie, C. Akoma, I. M. Mejeha, K. Okeoma, K. I. Mejeh
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引用次数: 9

摘要

采用重量法研究了大戟叶和豚鼠叶提取物对铝在0.25M NaOH中腐蚀的影响。结果表明,大戟叶提取物和豚草叶提取物对铝的腐蚀有抑制作用,其抑制作用取决于植物提取物的浓度和铝样品在含提取物的0.25M NaOH溶液中的暴露时间。Dialum guineense提取物对氢氧化钠中铝的缓蚀性能最好,这可能是由于其吸附的提取物分子取向呈平面状。随着氢氧化钠浓度的降低,所测试的抑制剂的抑制效率提高。实验数据符合Langmuir和Temkin吸附等温线,得到的吸附表观活化能值和符号表明,抑制剂分子具有混合抑制机制。
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Corrosion Control of Aluminium Alloy in Alkaline Solution Using Some Leave Extracts
The effect of Euphorbia hirta and Dialum guineense leave extracts on the corrosion of aluminium in 0.25M NaOH was investigated using gravimetric technique. It was shown that the presence of Euphorbia hirta and Dialum guineense leave extracts inhibited the corrosion of aluminium in the test solutions and that the inhibition efficiency depended on the concentration of the plant extract as well as on the time of exposure of the aluminium samples in 0.25M NaOH solu- tions containing the extracts. Dialum guineense extract shows the best inhibition capability for aluminium corrosion in so- dium hydroxide, probably, this is due to the planer orientation of the adsorbed extract molecules. Inhibition efficiency of the inhibitors tested increases with decreasing sodium hydroxide concentrations. The experimental data complied to both Langmuir and Temkin adsorption isotherms and the value and sign of the apparent activation energy of adsorption obtained suggests that inhibitor molecules have mixed inhibition mechanism.
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