油棕树干淀粉生物聚合物膜的特性及制备使用山梨醇增塑剂

A. Hamzah
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引用次数: 1

摘要

对油棕干淀粉制备生物聚合物薄膜进行了研究。油棕榈干淀粉与增塑剂山梨醇(变化量为2:0,8)混合制成生物聚合物薄膜;2:1,0;2:1,2 (g/mL),然后将膜模制在亚克力板上,在40℃烤箱中烘干24小时。薄膜表征结果表明,生物聚合物的最佳变化量为2:0,8 (g/mL),抗拉强度为4.26 MPa,伸长率为1.87%,膜厚为0.16 mm,可作为添加2 g壳聚糖建立生物聚合物薄膜的参考。拉伸强度测试值为14000 MPa,延伸率测试值为3.20%,薄膜厚度测试值为0.10 mm。差示扫描量热法(DSC)结果显示,吸热温度升高11575 oC,放热温度升高394956 oC。热重分析(TGA)结果表明,在340,10℃时膜开始分解。肿胀率为63,176%。傅里叶变换红外(FT-IR)结果表明,生物聚合物薄膜只发生物理相互作用。同时,抗菌活性分析表明,在生物聚合物膜上添加壳聚糖对金黄色葡萄球菌和大肠杆菌有明显的抑制作用,抑菌指数分别为0.625。SEM分析表明,壳聚糖添加后的膜比未添加壳聚糖的膜更均匀。壳聚糖的加入有利于提高生物聚合物薄膜的物理力学性能。
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The Characteristics and The Making of Biopolymer Film from Oil Palm Trunk Starch (Elaeis guineensis Jacq.) Using Sorbitol Plasticizer
The research about of the biopolymers film from oil palm trunk starch had been done.  Biopolymers  film  made  by  mixing  of  oil  palm  trunk  starch  (Elaeis guineensis Jacq.) and plasticizer sorbitol with the variation was 2:0,8 ; 2:1,0 ;2:1,2 (g/mL), then the film was molded on acrylic plate and dried in an oven at 40°C for 24  hours.  The results of  the film characterization  show that  the best variation of biopolymers on comparison 2:0,8 (g/mL) with the value of tensile strength was 4,26 MPa, percentage of elongation was 1,87 %, and film thickness was 0,16 mm, then it can be used as reference for addition 2 gram chitosan on the establishment of biopolymer film. It was characterized by tensile strength test with value was 14,00 MPa, pencentage of elongation with value was 3,20 %, and film thickness  with  value  was  0,10  mm.  The  results  of  Differential  Scanning Calorimetry  (DSC)  showed  increasing  of  the  endothermic  temperature  was 115,75 oC and exothermic temperature was 394,56 oC. The results of Thermal Gravimetry Analysis (TGA) showed that at a temperature of 340,1 0C the film to start decomposed. The value of % Swelling was 63,176%. The Fourier Transform Infra  Red  (FT-IR)  result  showed  that  in  biopolymers  film  occurs  physical interaction  only.  As  well  as,  the  antibacterial  activity  analysis  showed  that addition of chitosan on biopolymer film made Staphylococcus Aureus and Escherichia Coli bacterial was great inhibited with index antibacterial value of 0,625  respectively.  From SEM analysis showed  that film had  been  added by chitosan more homogenous than film without chitosan addition. The presence of chitosan addition tend to increase the physical and mechanical  properties of biopolymer film.
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