大学化学实验事故可预见性案例研究

K. Mizuno, Kaori Ueki, T. Akitsu
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引用次数: 3

摘要

本研究针对高校化学实验中使用的化学物质的性质或数据,探讨了火灾事故的预测方法。参考日本《消防法》中有害化合物及其性质,从理学院化学系本科普通化学实验教材中选取具有潜在危险的操作方法。此外,还从一些数据库中检索了以前与这种危险化合物和实验操作有关的火灾事故的例子。比较这两个事实,我们得出的结论是,大多数火灾事故是可预测的,一些困难的情况下(i)需要化学实验的常识(隐性知识与经验)和(ii)是危险化合物的状态依赖属性,e。g。非常活泼的纳米颗粒。研究结果还将提出未来人工智能辅助预测火灾事故的可能性、需要学习的数据范围以及遗留的技术问题。[3] Cl和滴几毫升水,溶解好。在冰浴中冷却溶液时,加入6- 7ml的3mol /L氯化氢。要小心,因为溶液会剧烈起泡。加入3mol /L氯化氢后,缓慢加入约5ml浓缩氯化氢,然后在通风柜内的热板上加热冷凝,直至溶液凝固成绿色晶体。固化后放凉,再加入少量冷水,然后用甲醇清洗。擦干手表玻璃。文本
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Case Studies on Predictability in University Chemistry Experiment Accidents
In this study, we investigated prediction of fire accidents of university’s chemical experiments based on properties or data of chemicals used. By referencing hazardous compounds and their properties in the Fire Service Act in Japan, potentially dangerous operations were picked up from the textbook of General Chemistry Laboratory for undergraduate students in Department of Chemistry, Faculty of Science, University of Science. Moreover, previous examples of fire accidents associated with such hazardous compounds and experimental operations were also searched from some databases. Comparing both facts, we concluded that most of fire accidents are predictable, and some difficult cases (i) required common sense for chemical experiments (implicit knowledge with experience) and (ii) are state-dependent properties of the hazardous compounds, e . g . very reactive nanoparticles. The results will also suggest possibility of AI-aided prediction of fire accidents in the future, the range of data required to be learnt, and remaining technical problems. 3 )] Cl and drop a few mL of water and dissolve well. While cooling the solution in an ice bath, add 6-7 mL of 3 mol/L hydrogen chloride. Care should be taken, since the solution will bubble vigorously. After adding 3 mol/L hydrogen chloride, add about 5 mL of concentrated hydrogen chloride slowly, then heat and condense on a hot plate inside a fume hood until the solution solidifies into green crystals. After it solidifies, let cool, then add a small amount of cold water, then, wash with methanol . Dry well on watch glass. Text
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