苄基甲基丙烯酸酯的合成及自由基聚合

V.A. Vahabova
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引用次数: 0

摘要

本文介绍了新单体苯并氨基丙烯酸酯的合成情况。通过物理和化学方法研究确定了其组成和结构。研究了自由基在质量和苯溶液中的均聚反应规律,以期研制一种新型医用高分子杀菌剂。结果表明,在这些条件下,聚合通过乙烯键进行,没有诱导期,以恒定的初始速率进行,没有产生副产物,随着可溶聚合物的形成,转化率单调增加高达92%。通过元素分析和光谱分析确定了聚合物的组成和结构。结果表明,该聚合物对大肠杆菌和金黄色葡萄球菌具有较强的生物杀灭活性,毒性较低,可作为生物杀灭制剂、医药剂型载体等多种用途。此外,该聚合物还具有光学半透明性,可用于光学领域。
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SYNTHESIS AND RADICAL POLYMERIZATION OF BENZAMIDMETACRYLATE
The data on the synthesis of the new monomer benzamidmetacrylate are presented in the article. Its composition and structure were established by physical and chemical methods of research. The regularities of radical homopolymerization reactions in mass and in benzene solution were studied with the aim of creating a new biocidal polymeric material for medical preparations. It is shown that polymerization under these conditions proceeds through the vinyl bond, without an induction period, at a constant initial rate without the formation of by-products, a monotonic increase in conversion up to 92% with the formation of a soluble polymer is observed. The composition and structure of the obtained polymer were established by elemental and spectral analyses. It showed that the polymer was characterized by a low toxicity at a significant biocidal activity towards E.coli and St.Aureus and that this polymer can be used in various fields, in particular as a biocidal preparation, a carrier of dosage forms in medicine. In addition, this polymer also exhibites optical translucency and can be used in optics.
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