{"title":"染料敏化太阳能电池中作为电子传递介质的TiO2浆料的粒径变化","authors":"Mohd Nizar Bin Zainol, M. H. Mamat","doi":"10.1109/SCORED.2016.7810081","DOIUrl":null,"url":null,"abstract":"Dye-sensitized solar cells (DSSC) belong to the third-generation solar cells and have been actively investigated due to their low cost and ease of fabrication. Dye-sensitized solar cells (DSSCs) based on titanium dioxide (TiO2) nanoparticles in mesoporous oxide have been intensively investigated since the first high efficiency cell was reported by O'Regan and Grätzel in 1991. In this paper, the effect of composition of micro/nano powder size TiO2 nanostructured in the mesoporous oxide layer was studied. The micro/nano powder, titanium dioxide have been successfully deposited on the transparent conductive oxide substrate using the screen printing technique. The effect of composition of (100% nanopowder), (75% nanopowder/25% micropowder), (50% nanopowder/50% micropowder), (25% nanopowder/75 micropowder and 100% micropowder) size of TiO2 nanostructured being studied. The deposited Titanium Dioxide films were characterized by field emission scanning electron microscope (FESEM) and Solar Simulator. The best efficiency of 3.46% under AM 1.5 was attained with a composition of (50% nanopowder/50% micropowder). The properties of TiO2 in term of thickness and total of adsorbed dye are not the only factors which have an influence on the overall conversion efficiency of dye sensitized solar cell. The combination of high light scattering and moderate surface area able to improve the performance of the dye sensitized solar cell.","PeriodicalId":6865,"journal":{"name":"2016 IEEE Student Conference on Research and Development (SCOReD)","volume":"148 1","pages":"1-5"},"PeriodicalIF":0.0000,"publicationDate":"2016-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Content variation of particle size in TiO2 paste as medium for electron transportation in dye sensitized solar cell\",\"authors\":\"Mohd Nizar Bin Zainol, M. H. Mamat\",\"doi\":\"10.1109/SCORED.2016.7810081\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Dye-sensitized solar cells (DSSC) belong to the third-generation solar cells and have been actively investigated due to their low cost and ease of fabrication. Dye-sensitized solar cells (DSSCs) based on titanium dioxide (TiO2) nanoparticles in mesoporous oxide have been intensively investigated since the first high efficiency cell was reported by O'Regan and Grätzel in 1991. In this paper, the effect of composition of micro/nano powder size TiO2 nanostructured in the mesoporous oxide layer was studied. The micro/nano powder, titanium dioxide have been successfully deposited on the transparent conductive oxide substrate using the screen printing technique. The effect of composition of (100% nanopowder), (75% nanopowder/25% micropowder), (50% nanopowder/50% micropowder), (25% nanopowder/75 micropowder and 100% micropowder) size of TiO2 nanostructured being studied. The deposited Titanium Dioxide films were characterized by field emission scanning electron microscope (FESEM) and Solar Simulator. The best efficiency of 3.46% under AM 1.5 was attained with a composition of (50% nanopowder/50% micropowder). The properties of TiO2 in term of thickness and total of adsorbed dye are not the only factors which have an influence on the overall conversion efficiency of dye sensitized solar cell. The combination of high light scattering and moderate surface area able to improve the performance of the dye sensitized solar cell.\",\"PeriodicalId\":6865,\"journal\":{\"name\":\"2016 IEEE Student Conference on Research and Development (SCOReD)\",\"volume\":\"148 1\",\"pages\":\"1-5\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2016 IEEE Student Conference on Research and Development (SCOReD)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/SCORED.2016.7810081\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2016 IEEE Student Conference on Research and Development (SCOReD)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/SCORED.2016.7810081","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
染料敏化太阳能电池(Dye-sensitized solar cells, DSSC)属于第三代太阳能电池,因其成本低、易于制造而受到人们的积极研究。自1991年O'Regan和Grätzel报道了第一种高效电池以来,基于介孔氧化物中二氧化钛(TiO2)纳米颗粒的染料敏化太阳能电池(DSSCs)得到了广泛的研究。本文研究了介孔氧化层中微/纳米粉末级TiO2纳米结构的组成对其性能的影响。采用丝网印刷技术成功地将微纳粉末二氧化钛沉积在透明导电氧化物衬底上。研究了(100%纳米粉)、(75%纳米粉/25%微粉)、(50%纳米粉/50%微粉)、(25%纳米粉/ 75%微粉和100%微粉)组成对TiO2纳米结构的影响。采用场发射扫描电镜(FESEM)和太阳模拟器对制备的二氧化钛薄膜进行了表征。当纳米粉/微粉比例为50%时,在AM 1.5下的效率为3.46%。TiO2在厚度和吸附染料总量方面的性能并不是影响染料敏化太阳能电池整体转化效率的唯一因素。高光散射和中等表面积的结合能够提高染料敏化太阳能电池的性能。
Content variation of particle size in TiO2 paste as medium for electron transportation in dye sensitized solar cell
Dye-sensitized solar cells (DSSC) belong to the third-generation solar cells and have been actively investigated due to their low cost and ease of fabrication. Dye-sensitized solar cells (DSSCs) based on titanium dioxide (TiO2) nanoparticles in mesoporous oxide have been intensively investigated since the first high efficiency cell was reported by O'Regan and Grätzel in 1991. In this paper, the effect of composition of micro/nano powder size TiO2 nanostructured in the mesoporous oxide layer was studied. The micro/nano powder, titanium dioxide have been successfully deposited on the transparent conductive oxide substrate using the screen printing technique. The effect of composition of (100% nanopowder), (75% nanopowder/25% micropowder), (50% nanopowder/50% micropowder), (25% nanopowder/75 micropowder and 100% micropowder) size of TiO2 nanostructured being studied. The deposited Titanium Dioxide films were characterized by field emission scanning electron microscope (FESEM) and Solar Simulator. The best efficiency of 3.46% under AM 1.5 was attained with a composition of (50% nanopowder/50% micropowder). The properties of TiO2 in term of thickness and total of adsorbed dye are not the only factors which have an influence on the overall conversion efficiency of dye sensitized solar cell. The combination of high light scattering and moderate surface area able to improve the performance of the dye sensitized solar cell.