超声辐照在三酸铜催化下一锅法合成h -苯并[f]铬-2-基(苯基)甲烷衍生物

Tamrat Yimenu Zeleke, K. Turhan, Z. Turgut
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引用次数: 0

摘要

以Cu(OTf) 2为催化剂,在超声波照射下,以2-萘酚、各种芳醛和苯甲酰丙酮或1,3-二苯基-1,3-丙二酮为原料,进行一锅缩合反应,制备了一种快速、高效、环保的萘吡喃合成工艺。该方法具有反应干净、方法简单、反应时间短、收率高、催化剂经济等优点。
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One-pot Synthesis of 1H-benzo[f]chromen-2-yl (phenyl)methanone Derivatives in the Presence of Copper Triflate as Catalyst Using Ultrasonic Irradiation
A rapid, efficient and environment-friendly protocol for the synthesis of naphthopyranes has been developed by one-pot condensation of 2-naphthol, various aromatic aldehydes and benzoylacetone or 1,3-diphenyl-1,3-propandione in the presence of Cu(OTf) 2 as catalyst under ultrasonic irradiation. The present approach offers the advantages of clean reaction, simple methodology, short reaction time, high yield and economic availability of the catalyst.
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