气候变化对碳致腐蚀起始概率的影响

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-08-23 DOI:10.3311/ppci.22101
Mostafa Hassan, L. Amleh
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引用次数: 0

摘要

近年来,气候变化对基础设施,特别是钢筋混凝土(RC)桥梁的影响迅速增加。这些后果主要是由二氧化碳排放的激增所驱动的,这显著影响了RC结构的碳化深度。本研究旨在探讨RC桥梁构件碳化诱发腐蚀的可能性。为了实现这一目标,该研究采用了一系列从30到50毫米不等的混凝土覆盖层,并考虑了水泥含量为400、350和250 kg/m3的不同混凝土混合物。本研究采用蒙特卡罗模拟方法,考虑不同的代表性浓度路径(rcp),分别考虑RCP2.6(低排放情景)和RCP8.5(高排放情景)两种排放情景。通过分析预计的二氧化碳浓度和最高温度,该研究为RC桥梁的潜在腐蚀引发风险提供了见解。研究结果表明,与RCP8.5情景下的400 kg/m3相比,当水泥含量为250 kg/m3时,PCICI显著增加了66.3%,特别是当到2100年使用30 mm的混凝土覆盖层时。研究还表明,在RCP2.6和RCP8.5两种情况下,无论水泥含量和持续时间的变化如何,当混凝土覆盖层设置为45和50 mm时,PCICI都接近于接近零的近似值。
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Influence of Climate Change on Probability of Carbonation-Induced Corrosion Initiation
The consequences of climate change on infrastructure, particularly reinforced concrete (RC) bridges, have rapidly increased in recent years. These consequences are primarily driven by the surge in CO2 emissions, which significantly impacts the carbonation depth of RC structures. This study aims to investigate the probability of carbonation-induced corrosion initiation (PCICI) in RC bridge elements. To achieve this, the investigation incorporates a range of concrete covers, varying from 30 to 50 mm, and considers different concrete mixes with cement contents of 400, 350, and 250 kg/m3. The investigation utilizes the Monte-Carlo simulation method, considering different representative concentration pathways (RCPs) to account for two emission scenarios: RCP2.6 (low emission scenario) and RCP8.5 (high emission scenario). By analyzing projected CO2 concentrations and maximum temperature, the study provides insights into the potential corrosion initiation risks in RC bridges. The findings indicated a significant 66.3% increase in PCICI for a cement content of 250 kg/m3, compared to 400 kg/m3, under the RCP8.5 scenario, specifically when using a concrete cover of 30 mm by 2100. The study also revealed that the PCICI approached an approximate value of zero when concrete covers were set at 45 and 50 mm regardless of the variations in cement contents and the duration considered, for both the RCP2.6 and RCP8.5 scenarios.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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