{"title":"一些不对称取代的1,3-二恶烷的核磁共振研究","authors":"V. Jones, J. Ladd","doi":"10.1039/J29710000567","DOIUrl":null,"url":null,"abstract":"The n.m.r. spectra of 14 asymmetrically substituted 1,3-dioxans have been examined and their temperature-dependence has provided information on the conformational requirements of the substituents. Thermodynamic parameters for the ring inversion process could be evaluated for six of these molecules.","PeriodicalId":17268,"journal":{"name":"Journal of The Chemical Society B: Physical Organic","volume":"39 1","pages":"567-570"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Nuclear magnetic resonance studies of some asymmetrically substituted 1,3-dioxans\",\"authors\":\"V. Jones, J. Ladd\",\"doi\":\"10.1039/J29710000567\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The n.m.r. spectra of 14 asymmetrically substituted 1,3-dioxans have been examined and their temperature-dependence has provided information on the conformational requirements of the substituents. Thermodynamic parameters for the ring inversion process could be evaluated for six of these molecules.\",\"PeriodicalId\":17268,\"journal\":{\"name\":\"Journal of The Chemical Society B: Physical Organic\",\"volume\":\"39 1\",\"pages\":\"567-570\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society B: Physical Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J29710000567\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society B: Physical Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J29710000567","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Nuclear magnetic resonance studies of some asymmetrically substituted 1,3-dioxans
The n.m.r. spectra of 14 asymmetrically substituted 1,3-dioxans have been examined and their temperature-dependence has provided information on the conformational requirements of the substituents. Thermodynamic parameters for the ring inversion process could be evaluated for six of these molecules.
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