蒙古绿松石的成分特征

L. Jia, Yang Ming-xing, L. Ling
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摘要

蒙古的绿松石颜色丰富,从蓝色到绿色不等。为了丰富蒙古绿松石的成分研究,本研究采用电子探针微量分析(EPMA)和激光烧蚀等离子体质谱(LA-ICP-MS)测定了蒙古绿松石的主要成分、微量元素和稀土元素(REE)的含量。Al2O3、P2O5、CuO和TFeO的含量分别为35.22% ~ 36.73%、34.34% ~ 35.84%、8.27% ~ 9.24%和2.20% ~ 3.76%。样品的TFeO / CuO比值随着颜色由蓝色变为绿色而增大。随着Fe3+含量的增加,样品的绿色色调增加。砷含量高达1 453.9 ~ 1 760.3 mg/kg。EDS扫描表明,As均匀分布在样品衬底中。样品中Sr、Ba、Pb的含量高于安徽、陕西、湖北等省。U含量与安徽马鞍山和安康绿松石样品相似,低于湖北云阳地区和竹山地区。稀土元素有两种不同的分布模式,一种为右倾分布,重、轻稀土分异,Eu损失不明显;另一个富集中稀土,轻、重稀土差异相对不显著,Eu呈正异常。根据分布曲线的差异,推断绿松石矿化经历了低温热液交代和风化淋滤两个阶段。前者稀土含量高于后者,轻稀土富集,后者丢失,但中稀土和重稀土含量与前者一致。研究确定了该地区绿松石的成分特征,推断了绿松石的成因,为区分蒙古绿松石产地提供了依据。
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Composition Characteristic of Turquoise from Mongolia
The turquoise from Mongolia is rich in colour, ranging from blue to green. To enrich the study on the composition of turquoise from Mongolia, this study determined the contents of main components, trace elements, and rare earth elements(REE) by electron probe microanalysis (EPMA) and laser ablation plasma mass spectrometer (LA-ICP-MS). The content of Al2O3, P2O5, CuO and TFeO were 35.22%-36.73%, 34.34%-35.84%, 8.27%-9.24% and 2.20%-3.76% respectively. The TFeO / CuO ratio of the sample increased with the colour change from blue to green. As the increase of Fe3+ content, the green hue of the sample increases. The content of As was as high as 1 453.9-1 760.3 mg/kg. The EDS scanning showed that As was uniform distributed in the sample substrate. The contents of Sr, Ba, and Pb in the samples were higher than those in Anhui, Shaanxi, and Hubei provinces. The U content was similar to that in turquoise samples from Ma'anshan and Ankang of Anhui Province, and lower than that in Yunyang district and Zhushan area of Hubei Province. There were two different patterns of REE distribution, one was right inclined, and the heavy and light rare earth were differentiated, and Eu loss was not obvious; the other was rich in medium rare earth, and the difference between light and heavy rare earth was relatively insignificant, and Eu showed positive anomaly. According to the difference of distribution curves, it was inferred that there were two stages of mineralization of turquoise, low temperature hydrothermal metasomatism and weathering leaching. The rare earth content of the former was higher than that of the latter, and the light rare earth was enriched, while the latter was lost, but the contents of medium rare earth and heavy rare earth were consistent with the former. The author studied and determined the composition characteristics of turquoise in this area and infers the genesis of turquoise and provided the basis for distinguishing the origin of turquoise from Mongolia.
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