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Inclusion Characteristic of Blue Sapphire from Australia 澳大利亚蓝蓝宝石的内含物特征
Pub Date : 2021-09-01 DOI: 10.15964/J.CNKI.027JGG.2021.05.003
Fang Fei, Diao Jingru, XU Yafen
The main purpose of this study is to observe the abundant inclusions of blue sapphire samples from Australia and analyze the composition of inclusions and provide a theoretical basis for the identification of its origin.The Leica M205A microscopic camera was used to finish the image acquisition of characteristic inclusions in blue sapphires from Australia. Laser Raman spectrometer was used to test inclusion composition.The result showed that the sapphire samples generally had obvious uneven colour distributions, healing fissures and partings. Some samples have hexagonal ribbons. Microscopic observation showed solid phase inclusions, tubular gas-liquid inclusions, fingerprint inclusions, and occasionally three-phase inclusions.Specially, some inclusions occur in the form of bicrystals.The inclusions identified by Raman spectroscopy include zircon, rutile, anatase, hematite, niobite, nepheline and CO2.
本研究的主要目的是观察澳大利亚蓝色蓝宝石样品中丰富的内含物,分析内含物的组成,为鉴定其产地提供理论依据。采用徕卡M205A显微相机完成澳大利亚蓝蓝宝石特征内含物的图像采集。采用激光拉曼光谱仪测定夹杂物成分。结果表明,蓝宝石样品普遍存在明显的颜色分布不均匀、愈合裂缝和分离现象。一些样品有六边形缎带。显微观察发现有固相夹杂物、管状气液夹杂物、指纹夹杂物,偶有三相夹杂物。特别地,有些夹杂物以双晶的形式出现。拉曼光谱鉴定的包裹体包括锆石、金红石、锐钛矿、赤铁矿、铌铁矿、霞石和CO2。
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引用次数: 0
Creation and Exploration Based on Traditional Granulation Technology 基于传统造粒技术的创新与探索
Pub Date : 2021-09-01 DOI: 10.15964/J.CNKI.027JGG.2021.05.011
Guoxing Tao, Liu Bin
The traditional granulation technology cannot meet the concise aesthetic needs of modern people and is facing extinction in the development of society because of its obvious shape of historical symbols and the complicated production process. This paper introduced the principle of traditional granulation technology, analyzed the advantages and disadvantages of powder welding and liquid diffusion method in welding, and obtained the differences between plane modeling and three-dimensional modeling in welding. After continuous experiments, it was found that modern industrial auxiliary materials could improve the production efficiency and simplify the traditional granulation process. This study made new use of the ancient method, tried the non-carcass body modeling, blurred the religious history decorative pattern, implication and other patterns and symbols, and the natural forms and colours in the modern social environment are integrated into the creation.
传统造粒工艺因其历史符号形态明显,生产工艺复杂,已不能满足现代人简洁的审美需求,在社会发展中面临灭绝。本文介绍了传统造粒技术的原理,分析了粉末焊接和液体扩散法在焊接中的优缺点,得出了焊接中平面建模和三维建模的区别。经过不断的实验,发现现代工业辅料可以提高生产效率,简化传统造粒工艺。本研究新用古法,尝试了非尸体造型,模糊了宗教历史纹饰、寓意等图案和符号,将现代社会环境中的自然形态和色彩融入创作之中。
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引用次数: 0
Status Quo of Taishan Jade Product in Jiangmen and Its Practice of Creative Innovation 江门泰山玉石产品现状及创新实践
Pub Date : 2021-09-01 DOI: 10.15964/J.CNKI.027JGG.2021.05.010
Chen Qingliu, Gao Hancheng
Taishan area is rich in jade and tourism resources. After years of development, it has formed a certain scale and a series of paths including raw jade material mining, production and processing, product design, production and sales etc. Through continuous investigation, it is found that the jade industry in this region is scattered, and there is no dense jade industry with a certain competitive brand. The main problems are : (1) The expression form of Taishan jade products are simple and the product creativity and innovation is insufficient and lack of vitality; (2) Lack of professional talents; (3) Lack of influential brand and the added value of Taishan jade products is low; (4) Limited product sales, communication and promotion mechanism, narrow radiation area and other problems. Based on the above problems, this paper investigates the status quo of Taishan jade products, and discusses the integration of regional tourism resources to increase the added value of products and the innovation of product design and development model. And to explore and practice ways to address the lack of creative innovation in Taishan jade products, which may provide reference for the design and innovation of Taishan jade products, in the hope of helping the development of Taishan jade industry and make the Taishan jade culture "come to live and become famous".
泰山地区有丰富的玉石和旅游资源。经过多年的发展,形成了一定规模的玉石原料开采、生产加工、产品设计、生产销售等一系列路径。通过不断的调查发现,该地区的玉石产业较为分散,没有密集的具有一定竞争品牌的玉石产业。主要问题有:(1)泰山玉器产品表现形式单一,产品创意创新不足,缺乏生命力;(2)专业人才缺乏;(3)缺乏有影响力的品牌,泰山玉石产品附加值低;(4)产品销售、沟通推广机制有限,辐射区域狭窄等问题。基于以上问题,本文对泰山玉石产品现状进行了调查,并对整合区域旅游资源提高产品附加值和创新产品设计开发模式进行了探讨。并探索和实践解决泰山玉石产品创意创新不足的途径,为泰山玉石产品的设计创新提供参考,以期助力泰山玉石产业的发展,使泰山玉石文化“活起来,出名”。
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引用次数: 0
Chromaticity Study of Emerald under Chelsea Filter 切尔西滤镜下祖母绿色度的研究
Pub Date : 2021-09-01 DOI: 10.15964/J.CNKI.027JGG.2021.05.002
Zhou Qingchao, Liu Hao, A. Shen
In conventional gem identification methods, whether the emeralds turn red under the Chelsea filter can be used as an auxiliary evidence for emerald identification, but this identification standard has limitations. In order to more accurately describe the colour changes of emeralds under the Chelsea filter, this article applied the colorimetry method to convert the transmittance spectra that passed through the Charles filter into chromaticity coordinates. Thus, the colour changes of emeralds under Chelsea filter can be presented in the form of data. This article first studied the influence of testing angle of spectra, contact way between emerald and Chelsea filter, and model difference of Chelsea filters and other factors on the emerald's chromaticity under Chelsea filter. Then, the optical loss was analyzed during the process of passing through the Chelsea filter. Based on the optical loss, the modulation algorithm of the Chelsea filter for emeralds' spectra was established. The distribution of colour coordinates on the CIE 1931 chromaticity diagram corresponding to the natural emerald and synthetic emerald spectra modulated by Chelsea filter is identifiable. The location distribution of chromaticity coordinates can be used as a basis to distinguish natural emeralds from synthetic emeralds to a certain extent.
在传统的宝石鉴定方法中,祖母绿在切尔西滤镜下是否变红可以作为祖母绿鉴定的辅助证据,但这一鉴定标准存在局限性。为了更准确地描述祖母绿在切尔西滤光片下的颜色变化,本文应用比色法将通过查尔斯滤光片的透射光谱转换为色度坐标。这样,祖母绿在切尔西滤镜下的颜色变化就可以以数据的形式呈现出来。本文首先研究了光谱测试角度、祖母绿与切尔西滤光片接触方式、切尔西滤光片型号差异等因素对切尔西滤光片下祖母绿色度的影响。然后,分析了通过切尔西滤波器过程中的光损耗。基于光损耗,建立了祖母绿光谱切尔西滤波器的调制算法。由切尔西滤光片调制的天然祖母绿和合成祖母绿光谱对应的CIE 1931色度图上的颜色坐标分布是可识别的。色度坐标的位置分布在一定程度上可以作为区分天然祖母绿和合成祖母绿的依据。
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引用次数: 0
Gemmological Characteristic of Spinel Associated Colourless Sapphire 尖晶石伴生无色蓝宝石的宝石学特征
Pub Date : 2021-09-01 DOI: 10.15964/J.CNKI.027JGG.2021.05.004
L. Jia, Diao Jingru, He Chong
The gemmological characteristics of a kind of sapphire that is associated with purple spinel were studied by EDXRF, Raman spectrometer, and fluorescence spectrometer. The sapphire sample contains 99.56% of Al2O3 and a certain amount of SiO2, CaO, TiO2, Fe2O3, Ga2O3, etc.Raman spectra showed that the colourless region is sapphire and the purple region is spinel; the inclusions are irregular and regular hexagonal solid graphite inclusion, gas inclusion that contains CO2, liquid inclusion that contains CH4, healing crack, etc. Fluorescence spectra showed no fluorescence in the colourless and purple substrate, and the peak positions of the fluorescence center of the luminescent part were near 440 nm and 460 nm. With the change of excitation wavelength from 365 nm to 390 nm, the red shift of the fluorescence center occurs. The relative intensity of the fluorescence center at 440 nm and 460 nm changed from strong to weak.
采用EDXRF、拉曼光谱仪和荧光光谱仪对紫尖晶石伴生蓝宝石的宝石学特征进行了研究。蓝宝石样品含有99.56%的Al2O3和一定量的SiO2、CaO、TiO2、Fe2O3、Ga2O3等,拉曼光谱显示无色区为蓝宝石,紫色区为尖晶石;夹杂物有不规则和规则的六边形固体石墨夹杂物、含CO2的气体夹杂物、含CH4的液体夹杂物、愈合裂纹等。荧光光谱显示,无色和紫色底物无荧光,发光部分荧光中心的峰位在440 nm和460 nm附近。随着激发波长从365 nm到390 nm的变化,荧光中心发生红移。荧光中心在440 nm和460 nm处的相对强度由强到弱变化。
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引用次数: 0
Oxygen Content and Colour Change Characteristic of Blood Amber from Myanmar 缅甸血琥珀的氧含量和颜色变化特征
Pub Date : 2021-09-01 DOI: 10.15964/J.CNKI.027JGG.2021.05.007
Dong Linling
The oxygen content and colour change characteristics of blood amber from Myanmar in different colours were nondestructively tested by Fourier transform infrared spectrometer and ultraviolet-visible spectrophotometer.The infrared spectroscopy testing results showed that the relative oxygen content of blood amber from Myanmar increases with its colour deepening, which suggests that the colour saturation was basically positively correlated with the oxygen content.With comparasion study of ultraviolet-visible spectra, the darker the colour of the samples, the closer its reflection curve inflection point is to the red end of the spectrum, i.e. the wavelength corresponding to the inflection point of the reflection curve appears "red shift" phenomenon; with the yellow tone deepening, the lightness increases, while the lightness decreases when the samples' colour transition from orange-ish red to brownish red. Combining the colour parameters of blood amber with oxygen content, it can be infered that the oxygen element is the main cause of the blood amber colour changes from orange-ish red to brownish red.
采用傅里叶变换红外光谱仪和紫外可见分光光度计对缅甸不同颜色血琥珀的氧含量和颜色变化特征进行了无损检测。红外光谱测试结果表明,缅甸血琥珀的相对氧含量随着颜色加深而增加,表明颜色饱和度与氧含量基本呈正相关。通过紫外可见光谱对比研究,样品颜色越深,其反射曲线拐点越靠近光谱的红端,即反射曲线拐点对应的波长出现“红移”现象;随着黄色调的加深,亮度增加,当样品的颜色从橙红色过渡到棕红色时,亮度降低。结合血琥珀的颜色参数与氧含量,可以推断出氧元素是血琥珀颜色由橙红色变为棕红色的主要原因。
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引用次数: 0
Identification Characteristic of Purple Jadeite Treated with Bleaching, Filling and Dyeing 紫硬石漂白、填充、染色的鉴定特征
Pub Date : 2021-09-01 DOI: 10.15964/J.CNKI.027JGG.2021.05.008
Y. Lu, D. Hui, Li Liujie, Cao Suqiao, Wang Feng, Guo Lianqiao, Yu Zhen
To explore the identification characteristics of purple jadeite that is treated with bleaching, filling and dyeing, the gem microscope, refractometer, UV-Vis-NIR spectropho-tometer, XRF spectrometer, DiamondViewTM, FTIR and Raman spectrometer were used. The results showed that the internal structure of the purple jadeite samples treated with bleaching, filling and dyeing was destroyed, and epoxy resin was detected by infrared spectrometer and Raman spectrometer. Strong Raman peak at 1 596 cm-1 could be the characteristic peak of dyes. Luminescent images showed the characteristic blue-violet fluorescence of the polymers formed by epoxy resin and organic dyes. The UV-Vis spectra of the purple jadeite samples treated with bleaching, filling and dyeing showed the absorption band of 200-350 nm, the absorption peak at 409 nm and the absorption band near 569 nm.The internal structure of the jadeite stained by the purple polishing powder was not damaged, and the purple colour only stained on the surface since the powder particles only remained on the surface. The luminescent images showed pinkish purple fluorescence, which was caused by the purple polishing powder. The strong central absorption band at 558 nm and the weak central absorption band at 611 nm can be seen in the UV-Vis spectra, which are different from the natural purple jadeite.
采用宝石显微镜、折光仪、紫外-可见-近红外光谱仪、XRF光谱仪、DiamondViewTM光谱仪、FTIR光谱仪和拉曼光谱仪对漂白、填充、染色后的紫翡翠进行鉴定。结果表明:经漂白、填充、染色处理后的紫色翡翠样品内部结构被破坏,并通过红外光谱仪和拉曼光谱仪检测到环氧树脂。1 596 cm-1处的强拉曼峰可以作为染料的特征峰。发光图像显示环氧树脂和有机染料形成的聚合物具有典型的蓝紫色荧光。经漂白、填充和染色处理的紫色翡翠样品紫外可见光谱显示,吸收波段在200 ~ 350 nm,吸收峰在409 nm,吸收波段在569 nm附近。被紫色抛光粉染色的翡翠内部结构没有被破坏,由于粉末颗粒只残留在表面,所以紫色只在表面染色。发光图像显示粉红色的紫色荧光,这是由紫色抛光粉引起的。在紫外-可见光谱中可见到558 nm处的强中心吸收带和611 nm处的弱中心吸收带,与天然紫玉不同。
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引用次数: 0
Identification Characteristic of "Recrystallized Snythetic Emerald" “再结晶合成祖母绿”的鉴定特征
Pub Date : 2021-09-01 DOI: 10.15964/J.CNKI.027JGG.2021.05.006
L. Lei, Shen Andy Hsitien
Recently, a kind of "recrystallized emerald" that claims to be created from natural emerald powder appeared in the market. In order to figure out its identification characteristics, on the basis of conventional gemmological testing, several other testing instruments were used, such as laser ablation inductively coupled plasma mass spectrometry, Fourier transform infrared spectrometer, ultraviolet visible spectrophotometer, and laser Raman spectrometer. The gemmological characteristics, chemical compositions and spectroscopy characteristics of 6 "recrystallized emerald" samples were tested. The inclusions of the samples include water-ripple pattern, gas-liquid two-phase inclusion, and healed cracks. The chemical composition of the sample is w(Al2O3)=18.48%~18.79%, w(SiO2)= 65.93%~66.19%, and w(Be)=49 700×10-6~50 700×10-6. The trace elements are rich in V and poor in Fe. The infrared spectra of the samples showed absorption peaks at 2 326, 5 102, 5 272, 5 456, 6 817, 7 143 cm-1 and a wide absorption band in the range of 4 000~3 400 cm-1, which indicates that the samples contain both type Ⅰ water and type Ⅱ water. The UV-Vis spectra of the samples showed absorption of Cr3+, Fe3+ and V3+in one category, and absorption of Cr3+ and V3+ in the other. Raman spectra of the samples showed the Be-O telescopic vibration (1 067 cm-1), deformation vibration of Si-O-Si (683 cm-1) and lattice vibration (321.5 cm-1). The results showed that the characteristics of the "recrystallized emeralds" accord with the characteristics of hydrothermal synthetic emeralds, and no evidence indicates natural genesis. The so-called "recrystallized emerald" is more a gimmick for businesses to attract customers. The "recrystallized emerald" should be correctly named as synthetic emerald.
最近,市场上出现了一种声称由天然祖母绿粉末制成的“再结晶祖母绿”。为了明确其鉴别特性,在常规宝石学检测的基础上,采用了激光烧蚀电感耦合等离子体质谱仪、傅里叶变换红外光谱仪、紫外可见分光光度计、激光拉曼光谱仪等多种检测仪器。对6个“再结晶祖母绿”样品的宝石学特征、化学成分和光谱特征进行了测试。样品的包裹体主要有水波纹型、气液两相包裹体和愈合裂纹。样品的化学成分为w(Al2O3)=18.48%~18.79%, w(SiO2)= 65.93%~66.19%, w(Be)=49 700×10-6~50 700×10-6。微量元素富V,贫Fe。红外光谱显示,样品在2 326、5 102、5 272、5 4556、6 817、7 143 cm-1处有较宽的吸收峰,在4 000~3 400 cm-1范围内,表明样品中既有Ⅰ型水,也有Ⅱ型水。样品的紫外可见光谱显示,一类吸收Cr3+、Fe3+和V3+,另一类吸收Cr3+和V3+。样品的拉曼光谱表现为Be-O伸缩振动(1 067 cm-1)、Si-O-Si变形振动(683 cm-1)和晶格振动(321.5 cm-1)。结果表明,“重结晶祖母绿”的特征符合热液合成祖母绿的特征,没有自然成因的迹象。所谓的“再结晶祖母绿”更多的是商家吸引顾客的噱头。“再结晶祖母绿”应正确命名为合成祖母绿。
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引用次数: 0
Characteristic and Identification of Bleached and Filled Aquamarine 漂白和填充海蓝宝石的特性及鉴定
Pub Date : 2021-09-01 DOI: 10.15964/J.CNKI.027JGG.2021.05.005
Jia Qiong, LI Guogui, Li Xueming, X. Yao, Wang Hailong, Luo Junqi
The aquamarine samples were collected from gem factories and jewelry markets, and the gemmological characteristics, infrared spectra and fluorescence images were tested and analyzed. The results showed that blue flashes and bubles can be seen in the sample when magnified. Infrared spectra showed a group of absorption peaks related to epoxy resin near 2 879, 2 932, 2 962, 3 035 cm-1 and 3 055 cm-1indicating that the samples have been filled. Through magnification, cracks can be seen on the surface of the samples. The fluorescence images under DiamondViewTM showed that bluish white fluorescence interlaces densely in the sample. The micro-infrared spectra showed the absorption peaks related to epoxy resin in the central area of sample slices, indicating that the sample structure was damaged and the filling degree was serious. Such samples should be named "bleached and filled aquamarine" according to the China national standard Gems-Nomenclature.
从宝石厂和珠宝市场采集海蓝宝石样品,对其宝石学特征、红外光谱和荧光图像进行测试和分析。结果表明,放大后的样品中可以看到蓝色闪光和气泡。红外光谱在2 879、2 932、2 962、3 035 cm-1和3 055 cm-1附近有一组与环氧树脂有关的吸收峰,表明样品已被填充。通过放大,可以看到试样表面有裂纹。DiamondViewTM下的荧光图像显示,样品中蓝白色荧光密集交错。微红外光谱显示样品切片中心区域存在与环氧树脂相关的吸收峰,说明样品结构被破坏,填充程度严重。按照中国宝石国标《宝石命名法》命名为“漂填海蓝宝石”。
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引用次数: 0
The Analysis of Supply, Demand and Market Value of Gemstones: Taking Peridot as An Example 宝石供求与市场价值分析——以橄榄石为例
Pub Date : 2021-09-01 DOI: 10.15964/J.CNKI.027JGG.2021.05.009
Gao Zhongqi, Yu Haiyang
The supply and demand of the market affect the use value of gemstone. Only sustainable and stable supply of the gemstone resource can continuously promote the consumption and meet the demand of the consumers, thus promot the realization of the gemstone value. In this paper, peridot was taken as the main research object, through extensive literature analysis, the development and change of supply-demand relationship of ancient and modern peridot was reviewed.By analyze the supply-demand relationship trend of red spinel which has the similar historical position and development process of peridot, this paper analyzed the reasons why the peridot is undervalued and its future value improvement. The results showed that the historical instability in the supply of peridot was the main reason of the decline in its popularity, and the serious of underestimation of its value today. At present, the newly discovered Yiqisong Nanshan Peridot Mine in China can provide a consistent and stable supply to the global peridot market, and the four advantages of untreated peridot products meet the needs of the Chinese and even global consumers. It can be predicted that with the stable exploitation of Yiqisong Nanshan Peridot Mine in China, the global peridot market will be continuously and stably supplied, and the peridot can gradually get rid of the current undervalued situation and return to its historical status. The research takes peridot as an example and provides a case of how gemstone supply impacts the demand and its value for the gemstone industry supply, demand and value of gemstone.
市场的供求关系影响着宝石的使用价值。只有宝石资源持续稳定的供应,才能不断促进消费,满足消费者的需求,从而促进宝石价值的实现。本文以橄榄石为主要研究对象,通过广泛的文献分析,回顾了古今橄榄石供需关系的发展变化。本文通过分析与橄榄石有着相似历史地位和发展过程的红尖晶石的供需关系趋势,分析了橄榄石被低估的原因和未来价值的提升。结果表明,历史上橄榄石供应的不稳定是其受欢迎程度下降的主要原因,也是当今橄榄石价值被严重低估的主要原因。目前,中国新发现的益奇松南山橄榄石矿可以为全球橄榄石市场提供持续稳定的供应,未经处理橄榄石产品的四大优势满足了中国乃至全球消费者的需求。可以预见,随着中国一歧松南山橄榄石矿的稳定开采,全球橄榄石市场将持续稳定供应,橄榄石将逐步摆脱目前被低估的局面,回归历史地位。本研究以橄榄石为例,为宝石行业的宝石供应、需求和价值提供了宝石供应如何影响需求及其价值的案例。
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引用次数: 0
期刊
Journal of Gems & Gemmology
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