Yingxin Zhao, Hao Hu, Shengyu Zhang, S. Feng, Yun Yang, Xiongjian Li, Shuijin Yang
{"title":"2-甲基咪唑修饰铁金属有机骨架作为高效亚甲基蓝吸附剂的研究","authors":"Yingxin Zhao, Hao Hu, Shengyu Zhang, S. Feng, Yun Yang, Xiongjian Li, Shuijin Yang","doi":"10.12982/cmjs.2022.104","DOIUrl":null,"url":null,"abstract":"Metal organic frameworks have a wide range of applications in the fi eld of environmental remediation. In this study, Fe-BDC/Fe-2MI composites were synthesized by one-pot solvothermal method. By studying the adsorption performance of methylene blue (MB) in wastewater, it was confi rmed that Fe-BDC/Fe-2MI has excellent adsorption properties. When the initial molar ratio of FeCl3 .6H2O: H2BDC: 2-MI is 1:1.5:10, the adsorbent has the best adsorption performance. At the same time, the effects of different pH (2-10), temperature (303-323K) and initial concentration of adsorbate (30-90mg/L) on the adsorption capacity were further explored. It was found that when pH=6.0, T=303K was favorable for Fe-BDC/Fe-2MI to adsorb MB. The adsorption process conformed to the Langmuir isotherm adsorption model, indicating that it was a monolayer adsorption which was a good adsorption process. Thermodynamic parameters show that the adsorption process is a spontaneous exothermic reaction. These results demonstrated that Fe-BDC/Fe-2MI composites possess potential practical application value.","PeriodicalId":9884,"journal":{"name":"Chiang Mai Journal of Science","volume":"284 1","pages":""},"PeriodicalIF":0.6000,"publicationDate":"2022-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"2-Methylimidazole-modifi ed Iron Metal-organic Framework as an Effi cient Methylene Blue Adsorbent\",\"authors\":\"Yingxin Zhao, Hao Hu, Shengyu Zhang, S. Feng, Yun Yang, Xiongjian Li, Shuijin Yang\",\"doi\":\"10.12982/cmjs.2022.104\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Metal organic frameworks have a wide range of applications in the fi eld of environmental remediation. In this study, Fe-BDC/Fe-2MI composites were synthesized by one-pot solvothermal method. By studying the adsorption performance of methylene blue (MB) in wastewater, it was confi rmed that Fe-BDC/Fe-2MI has excellent adsorption properties. When the initial molar ratio of FeCl3 .6H2O: H2BDC: 2-MI is 1:1.5:10, the adsorbent has the best adsorption performance. At the same time, the effects of different pH (2-10), temperature (303-323K) and initial concentration of adsorbate (30-90mg/L) on the adsorption capacity were further explored. It was found that when pH=6.0, T=303K was favorable for Fe-BDC/Fe-2MI to adsorb MB. The adsorption process conformed to the Langmuir isotherm adsorption model, indicating that it was a monolayer adsorption which was a good adsorption process. Thermodynamic parameters show that the adsorption process is a spontaneous exothermic reaction. These results demonstrated that Fe-BDC/Fe-2MI composites possess potential practical application value.\",\"PeriodicalId\":9884,\"journal\":{\"name\":\"Chiang Mai Journal of Science\",\"volume\":\"284 1\",\"pages\":\"\"},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2022-11-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chiang Mai Journal of Science\",\"FirstCategoryId\":\"103\",\"ListUrlMain\":\"https://doi.org/10.12982/cmjs.2022.104\",\"RegionNum\":4,\"RegionCategory\":\"综合性期刊\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MULTIDISCIPLINARY SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chiang Mai Journal of Science","FirstCategoryId":"103","ListUrlMain":"https://doi.org/10.12982/cmjs.2022.104","RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
2-Methylimidazole-modifi ed Iron Metal-organic Framework as an Effi cient Methylene Blue Adsorbent
Metal organic frameworks have a wide range of applications in the fi eld of environmental remediation. In this study, Fe-BDC/Fe-2MI composites were synthesized by one-pot solvothermal method. By studying the adsorption performance of methylene blue (MB) in wastewater, it was confi rmed that Fe-BDC/Fe-2MI has excellent adsorption properties. When the initial molar ratio of FeCl3 .6H2O: H2BDC: 2-MI is 1:1.5:10, the adsorbent has the best adsorption performance. At the same time, the effects of different pH (2-10), temperature (303-323K) and initial concentration of adsorbate (30-90mg/L) on the adsorption capacity were further explored. It was found that when pH=6.0, T=303K was favorable for Fe-BDC/Fe-2MI to adsorb MB. The adsorption process conformed to the Langmuir isotherm adsorption model, indicating that it was a monolayer adsorption which was a good adsorption process. Thermodynamic parameters show that the adsorption process is a spontaneous exothermic reaction. These results demonstrated that Fe-BDC/Fe-2MI composites possess potential practical application value.
期刊介绍：
The Chiang Mai Journal of Science is an international English language peer-reviewed journal which is published in open access electronic format 6 times a year in January, March, May, July, September and November by the Faculty of Science, Chiang Mai University. Manuscripts in most areas of science are welcomed except in areas such as agriculture, engineering and medical science which are outside the scope of the Journal. Currently, we focus on manuscripts in biology, chemistry, physics, materials science and environmental science. Papers in mathematics statistics and computer science are also included but should be of an applied nature rather than purely theoretical. Manuscripts describing experiments on humans or animals are required to provide proof that all experiments have been carried out according to the ethical regulations of the respective institutional and/or governmental authorities and this should be clearly stated in the manuscript itself. The Editor reserves the right to reject manuscripts that fail to do so.
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