Ag2O和rGO掺杂2-氨基对苯二甲酸Cu-MOFs光学带隙的调制

Maalathi Challa, M. Ambika, S. Usharani, S. Batakurki, B. Yallur
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引用次数: 3

摘要

掺杂铜金属的MOF在电磁波谱的紫外区显示出约1.5 eV的带隙。加入Ag2O和还原氧化石墨烯后,这种含铜的MOF变成纳米/MOF复合材料。MOF/ Ag2O和MOF/rGO的带隙分别为1.904 eV和1.639 eV。这种带隙的变化支持将它们用作紫外线和近可见光收获催化剂,也有助于增强化合物的机械、热和结构行为。MOF/nanoMO带隙的增强主要归因于量子尺寸效应。
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Modulation of Optical Band Gap of 2-Amino Terephthalic Acid Cu-MOFs Doped with Ag2O and rGO
The synthesized MOF with copper metal dopant has shown band gap around 1.5 eV which falls in the UV region of electromagnetic spectrum. This MOF with copper turns into nano/MOF composite with addition of Ag2O and rGO to it. The results of band gap of MOF/ Ag2O and MOF/rGO showed 1.904 eV and 1.639 eV respectively. This shift in band gap supports to use them as a UV and near visible light harvest catalyst and also assist in enhancing mechanical, thermal and structural behaviour of compounds. The enhancement of band gap of MOF/nanoMO is attributed to the quantum size effect.
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