{"title":"N4O3潜在七齿配体合成多金属Fe(II)和Mn(II)及其表征","authors":"A. Mustapha, S. Gani","doi":"10.4314/CSJ.V5I1","DOIUrl":null,"url":null,"abstract":"Potentially heptadentate (N4O3) tripodal Schiff-base ligand, tris(5-Bromo-2-hydroxybenzylaminoethyl)amine has been prepared and characterized using various spectroscopic methods. It is derived from the condensation reactions of tris(2-aminoethyl)amine (tren), with 3 equivalents of 5-bromo-2-hydroxybenzaldehyde. Iron(II) and Manganese(II) complexes of the resulting ligand were obtained from its reactions with Fe(II) and Mn(II) salts in absolute methanol for the metal to ligand ratio 2:3. These complexes were characterized by Solubility, Conductivity, IR and UV-VIS spectrometry, elemental analysis and mass spectrometry. Keywords : Iron, Manganese, Schiff- base, Tren5BrSal, tris-(2-aminoethyl)amine","PeriodicalId":9900,"journal":{"name":"ChemSearch Journal","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Characterization of Multimetallic Fe(II) and Mn(II) Using N4O3 Potentially Heptadentate Ligand\",\"authors\":\"A. Mustapha, S. Gani\",\"doi\":\"10.4314/CSJ.V5I1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Potentially heptadentate (N4O3) tripodal Schiff-base ligand, tris(5-Bromo-2-hydroxybenzylaminoethyl)amine has been prepared and characterized using various spectroscopic methods. It is derived from the condensation reactions of tris(2-aminoethyl)amine (tren), with 3 equivalents of 5-bromo-2-hydroxybenzaldehyde. Iron(II) and Manganese(II) complexes of the resulting ligand were obtained from its reactions with Fe(II) and Mn(II) salts in absolute methanol for the metal to ligand ratio 2:3. These complexes were characterized by Solubility, Conductivity, IR and UV-VIS spectrometry, elemental analysis and mass spectrometry. Keywords : Iron, Manganese, Schiff- base, Tren5BrSal, tris-(2-aminoethyl)amine\",\"PeriodicalId\":9900,\"journal\":{\"name\":\"ChemSearch Journal\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemSearch Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4314/CSJ.V5I1\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemSearch Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4314/CSJ.V5I1","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and Characterization of Multimetallic Fe(II) and Mn(II) Using N4O3 Potentially Heptadentate Ligand
Potentially heptadentate (N4O3) tripodal Schiff-base ligand, tris(5-Bromo-2-hydroxybenzylaminoethyl)amine has been prepared and characterized using various spectroscopic methods. It is derived from the condensation reactions of tris(2-aminoethyl)amine (tren), with 3 equivalents of 5-bromo-2-hydroxybenzaldehyde. Iron(II) and Manganese(II) complexes of the resulting ligand were obtained from its reactions with Fe(II) and Mn(II) salts in absolute methanol for the metal to ligand ratio 2:3. These complexes were characterized by Solubility, Conductivity, IR and UV-VIS spectrometry, elemental analysis and mass spectrometry. Keywords : Iron, Manganese, Schiff- base, Tren5BrSal, tris-(2-aminoethyl)amine
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