{"title":"丙咪嗪-氯原噻嗪三元配合物分光光度法测定钒","authors":"B. Starczewska","doi":"10.1081/TMA-120006683","DOIUrl":null,"url":null,"abstract":"ABSTRACT Sensitive methods for the spectrophotometric determination of trace amounts of vanadium(IV) are described. The methods utilize the ternary complexes formed by reacting vanadium(IV) with imipramine or chlorprothixene hydrochlorides in the presence of chrome azurol S and methylcellulose. The composition and the absorption spectra in the UV–VIS and IR regions of the ion association complexes are described.","PeriodicalId":17525,"journal":{"name":"Journal of Trace and Microprobe Techniques","volume":"49 1","pages":"377 - 384"},"PeriodicalIF":0.0000,"publicationDate":"2002-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"SPECTROPHOTOMETRIC DETERMINATION OF VANADIUM(IV) BY TERNARY COMPLEXES OF CHROME AZUROL S WITH IMIPRAMINE AND CHLORPROTHIXENE\",\"authors\":\"B. Starczewska\",\"doi\":\"10.1081/TMA-120006683\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT Sensitive methods for the spectrophotometric determination of trace amounts of vanadium(IV) are described. The methods utilize the ternary complexes formed by reacting vanadium(IV) with imipramine or chlorprothixene hydrochlorides in the presence of chrome azurol S and methylcellulose. The composition and the absorption spectra in the UV–VIS and IR regions of the ion association complexes are described.\",\"PeriodicalId\":17525,\"journal\":{\"name\":\"Journal of Trace and Microprobe Techniques\",\"volume\":\"49 1\",\"pages\":\"377 - 384\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-08-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Trace and Microprobe Techniques\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/TMA-120006683\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Trace and Microprobe Techniques","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/TMA-120006683","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
SPECTROPHOTOMETRIC DETERMINATION OF VANADIUM(IV) BY TERNARY COMPLEXES OF CHROME AZUROL S WITH IMIPRAMINE AND CHLORPROTHIXENE
ABSTRACT Sensitive methods for the spectrophotometric determination of trace amounts of vanadium(IV) are described. The methods utilize the ternary complexes formed by reacting vanadium(IV) with imipramine or chlorprothixene hydrochlorides in the presence of chrome azurol S and methylcellulose. The composition and the absorption spectra in the UV–VIS and IR regions of the ion association complexes are described.