丙咪嗪-氯原噻嗪三元配合物分光光度法测定钒

B. Starczewska
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引用次数: 6

摘要

建立了一种灵敏的分光光度法测定痕量钒(IV)的方法。该方法利用钒(IV)与丙咪嗪或盐酸氯原噻烯在azurrol S和甲基纤维素存在下反应形成的三元配合物。描述了离子缔合物的组成及其紫外-可见和红外吸收光谱。
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SPECTROPHOTOMETRIC DETERMINATION OF VANADIUM(IV) BY TERNARY COMPLEXES OF CHROME AZUROL S WITH IMIPRAMINE AND CHLORPROTHIXENE
ABSTRACT Sensitive methods for the spectrophotometric determination of trace amounts of vanadium(IV) are described. The methods utilize the ternary complexes formed by reacting vanadium(IV) with imipramine or chlorprothixene hydrochlorides in the presence of chrome azurol S and methylcellulose. The composition and the absorption spectra in the UV–VIS and IR regions of the ion association complexes are described.
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