环烯烃共聚物(COC)的固体核磁共振研究

Wu-Jang Huang, F. Chang, P. P. Chu
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引用次数: 8

摘要

在本文中,我们采用固态13C NMR技术、交叉极化/魔角旋转(CP/MAS)和单脉冲13C NMR来表征环烯烃共聚物的NB构象。13C CP/MAS谱分析表明,NB含量越高的共聚物产生的NB嵌段越多。此外,基于铌二元的构象能够在49-52 ppm区域诱导峰分裂。©2000 John Wiley & Sons, Inc[J] .高分子材料学报,2003,19 (2):559 - 563
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Solid‐state NMR study of cyclo‐olefin copolymer (COC)
In this article, we have applied solid-state 13C NMR techniques, cross-polarization/magic-angle spinning (CP/MAS), and single-pulse 13C NMR to characterize the NB conformation of the cyclo-olefin copolymer. The copolymers containing higher NB contents produce more NB blocks according to 13C CP/MAS spectral analysis. In addition, NB-dyad-based conformations are able to induce peak splitting in the region of 49–52 ppm. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 2554–2563, 2000
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来源期刊
CiteScore
5.90
自引率
0.00%
发文量
0
审稿时长
2.1 months
期刊介绍: Since its launch in 1946 by P. M. Doty, H. Mark, and C.C. Price, the Journal of Polymer Science has provided a continuous forum for the dissemination of thoroughly peer-reviewed, fundamental, international research into the preparation and properties of macromolecules. From January 2020, the Journal of Polymer Science, Part A: Polymer Chemistry and Journal of Polymer Science, Part B: Polymer Physics will be published as one journal, the Journal of Polymer Science. The merged journal will reflect the nature of today''s polymer science research, with physics and chemistry of polymer systems at the heart of the scope. You can continue looking forward to an exciting mix of comprehensive reviews, visionary insights, high-impact communications, and full papers that represent the rapid multidisciplinary developments in polymer science. Our editorial team consists of a mix of well-known academic editors and full-time professional editors who ensure fast, professional peer review of your contribution. After publication, our team will work to ensure that your paper receives the recognition it deserves by your peers and the broader scientific community.
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