二氧化硅/木质素磺酸盐杂化材料:制备与表征

Ł. Klapiszewski, J. Zdarta, Tomasz Szatkowski, M. Wysokowski, M. Nowacka, K. Szwarc-Rzepka, P. Bartczak, Katarzyna Siwińska-Stefańska, H. Ehrlich, T. Jesionowski
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引用次数: 28

摘要

本文报道了二氧化硅/木质素磺酸盐杂化材料的合成、表征及其应用前景。使用了三种类型的二氧化硅(Aerosil®200,Syloid®244和水合二氧化硅),以及木质素磺酸镁。利用傅里叶变换红外光谱、元素分析和比色分析间接证实了杂化材料合成方法的有效性。分散形态分析表明,每100份Syloid®244二氧化硅中加入10份木质素磺酸镁,可获得性能最佳的产品。大多数合成产物记录的相对较高的热稳定性表明这种材料作为聚合物填料的潜在用途。结果表明,材料的高电动稳定性也很重要。此外,良好的多孔结构特性表明二氧化硅/木质素磺酸盐体系作为有害金属离子和有害有机化合物的生物吸附剂的潜在用途。
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Silica/lignosulfonate hybrid materials: Preparation and characterization
The research reported here concerns the synthesis, characterization and potential applications of silica/lignosulfonate hybrid materials. Three types of silica were used (Aerosil®200, Syloid®244 and hydrated silica), along with magnesium lignosulfonate. The effectiveness of the hybrid material synthesis methodology was confirmed indirectly, using Fourier transform infrared spectroscopy, elemental and colorimetric analysis. Dispersive-morphological analysis indicates that the products with the best properties were obtained using 10 parts by weight of magnesium lignosulfonate per 100 parts of Syloid®244 silica. The relatively high thermal stability recorded for the majority of the synthesized products indicates the potential use of this kind of a material as a polymer filler. Results indicating the high electrokinetic stability of the materials are also of great importance. Additionally, the very good porous structure properties indicate the potential use of silica/lignosulfonate systems as biosorbents of hazardous metal ions and harmful organic compounds.
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