溶胶-凝胶法制备铁基费托催化剂及其活化研究

Muchammad Zainul Anwar, R. Tjahjanto, U. Hasanah
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引用次数: 0

摘要

随着石油消费量的逐年增加,需要努力通过开发新的可再生能源来增加能源储备。开发能源的一种方法是通过合成费托合成(FT)。FT是一种合成气(CO和h2的混合物)转化成长链烃混合物的反应。FT反应需要一种叫做FT催化剂的催化剂。迄今为止,许多研究考察了催化剂将合成气转化为长链碳氢化合物的有效性,但很少有关于催化剂表面存在的相组成的信息。为此,我们在不同的煅烧温度下合成了FT催化剂。本研究采用Fe(no3) 3为前体,Cu(no3) 2为启动子(20:1)。煅烧温度有300℃、500℃和700℃。采用XRD和SEM-EDX对催化剂进行了表征和分析。煅烧后的催化剂用co2和h2气体活化,然后用XRD和SEM-EDX对其进行表征。煅烧形成氧化铁相,活化形成碳化铁相和零铁相。
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Synthesis and Activation Study of Iron (Fe) Based Fischer Tropsch (FT) Catalyst Using Sol-gel Method
As oil consumption increases from year to year, efforts need to be made to increase energy reserves by developing new renewable energy. One way to develop energy sources is by the synthesis Fischer Tropsch (FT). FT is a synthetic gas conversion reaction (mixture of CO and H 2 ) into a long chain hydrocarbon mixture. The FT reaction requires a catalyst called the FT catalyst. So far, many studies that examine the effectiveness of catalysts in converting synthesis gas into long chain hydrocarbons, but rarely information about the composition of the phases that exist on the surface of the catalyst. To study about it, we synthesized FT catalysts at various variations of calcination temperature. Fe(NO 3 ) 3 as a precursor and Cu(NO 3 ) 2 as promoter (20:1) used in this study. The calcination temperature used are 300, 500, and 700°C. Characterization and analysis of catalysts were formed with XRD and SEM-EDX. Calcined catalysts were activated using CO 2 and H 2 gas and then re-characterized with XRD and SEM-EDX. Calcination results the formation of an iron oxide phase, while activation results the formation of iron carbide and zero Fe phases.
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