气体稳定电弧作为发射源测量振荡器强度的研究。铁中一些相对gf值的测定

M. Margoshes, B. F. Scribner
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引用次数: 11

摘要

研究了气体稳定电弧源在原子光谱中振荡强度测定中的应用。在这种源中,可以注入一种或多种元素的盐溶液,并在具有稳定光谱强度发射的电弧等离子体中直接激发元素。热源具有局部热平衡的特征,但径向温度梯度较大。实验表明,当两种元素在溶液中的电弧中引入时,在可能的实验误差范围内,放电中元素的相对浓度与溶液中元素的相对浓度相同。这一实验表明,电弧可用于确定绝对振荡器强度的一种方法。报道了在2900 ~ 4150 Å之间105行Fe - I的gf值的新测量结果,并将新值与先前的测量结果进行了比较。
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A Study of the Gas-Stabilized Arc as an Emission Source for the Measurement of Oscillator Strengths. Determination of Some Relative gf-Values for Fe I*
A study has been made of the application of the gas-stabilized arc source to the determination of oscillator strengths in atomic spectra. In this source, a solution of salts of one or more elements may be injected and the elements excited directly in an arc plasma with steady emission of spectral intensities. The source can be taken to be characterized by local thermal equilibrium, but with a large radial temperature gradient. An experiment indicates that when two elements are introduced into the arc in a solution, the relative concentrations of the elements in the discharge are the same as in the solution within the probable experimental error. This experiment indicates one way that the arc may be used for the determination of absolute oscillator strengths. New measurements are reported of the gf-values of 105 lines of Fe I between 2900 and 4150 Å, and the new values are compared with the results of earlier measurements.
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