碱金属离子掺杂对MAPbBr3钙钛矿纳米晶体光学性能的调控

M. Tabassum, Qasim Zia, S. Aslam, Yufei Wang, Jinshuai Zhang, M. Reece, Lei Su
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引用次数: 0

摘要

将Cs和Rb阳离子掺杂到MAPbBr 3pce中,以优化其形貌、晶体结构和光学性能。研究发现,铷离子的掺杂可以大大增强MAPBBr 3pce的光致发光强度,而铯离子的掺杂可以通过增加价键强度来提高结构的稳定性。本研究为基于混合阳离子pce的高性能光电器件的合成提供了有益的思路。
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Tuning the optical properties of MAPbBr3 perovskite nanocrystals via alkali metal ions doping
the doping of Cs and Rb cations into MAPbBr 3 PeNCs to optimize their morphology, crystal structure, and optical properties. It is found that rubidium cations doping can greatly enhance the photoluminescence intensity of the MAPBBr 3 PeNCs, whereas cesium cations can improve the structural stability owing to the increased valance bond intensity. This work provides useful thoughts for the synthesis of high-performance optoelectronic devices based on mixed-cation PeNCs.
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