天南星科活蕨中一个新的苯丙类糖苷

Tang Gui
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引用次数: 1

摘要

摘要从活体白藜芦醇(Remusatia vivipara Schott)的干球茎中分离得到一种新的苯丙类葡萄糖苷,即咖啡醇-3- o -b- d -葡萄糖苷。用波谱法和酸水解法确定了新化合物的结构。已知的化合物包括三种糖类(coniferin caffeyl酒精和松柏醇),三个neolignans(4、7、9、9“-tetrahydroxy-3 3”-dimethoxy-8-O-4 -neolign-7 ene, (7 r, 8 s) d7 3 3 -dimethoxy-4, 7, 9, 9 -tetrahydroxy-8-O-4 -neolignan-7-O-B-D-glucopyranoside,和dehydrodiconiferyl alcohol-4-B-D-glucoside],酰胺[(2 e, 4 e) -N-isobutyl-2 4-decadienamide],一个甾体皂苷(甲基proto-taccaoside)和三萜皂苷(saxifragifolin B)。所有化合物均为首次从该属植物中分离得到。
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A New Phenylpropanoid Glucoside from Remusatia vivipara(Araceae)
A new phenylpropanoid glucoside,caffeyl alcohol-3-O-b-D-glucopyranoside,together with nine known compounds,was isolated from the dry corms of Remusatia vivipara Schott. The structure of the new compound was determined by the spectroscopic method and acidic hydrolysis. The known compounds included three phenylpropanoids (coniferin,caffeyl alcohol and coniferyl alcohol),three neolignans [4,7,9,9'-tetrahydroxy-3,3'-dimethoxy-8-O-4'-neolign-7'-ene,(7R,8S)-D7'-3,3'-dimethoxy-4,7,9,9'-tetrahydroxy-8-O-4'-neolignan-7-O-B-D-glucopyranoside,and dehydrodiconiferyl alcohol-4-B-D-glucoside],an amide [(2E,4E)-N-isobutyl-2,4-decadienamide],a steroid saponin (methyl proto-taccaoside) and a triterpenoid saponin (saxifragifolin B ). All compounds were isolated from the genus Remusatia for the first time.
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