微波辅助百香果皮活性炭去除亚甲基蓝染料

M. A. Ahmad, Muhammad Aswar Eusoff, M. Khan, A. Khasri
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引用次数: 2

摘要

研究了百香果皮活性炭(PFPAC)对亚甲基蓝(MB)染料的吸附性能。百香果皮经微波辐照、二氧化碳气化等物理活化工艺制备PFPAC。通过响应面法(RSM)得到了最佳的制备条件,辐射功率为616 W,活化时间为6.24 min,对MB的去除率为85.66%,PFPAC收率为39.9%。优化后的PFPAC具有较高的比表面积、孔隙体积和固定碳含量,平均孔径分别为782.3 m2/g、0.422 cm3/g和0.295 nm。Freundlich等温线模型对吸附平衡数据拟合较好。吸附动力学符合准二级动力学模型。研究了百香果皮活性炭(PFPAC)对亚甲基蓝(MB)染料的吸附性能。百香果皮经微波辐照、二氧化碳气化等物理活化工艺制备PFPAC。通过响应面法(RSM)得到了最佳的制备条件,辐射功率为616 W,活化时间为6.24 min,对MB的去除率为85.66%,PFPAC收率为39.9%。优化后的PFPAC具有较高的比表面积、孔隙体积和固定碳含量,平均孔径分别为782.3 m2/g、0.422 cm3/g和0.295 nm。Freundlich等温线模型对吸附平衡数据拟合较好。吸附动力学符合准二级动力学模型。
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Microwave-assisted activated carbon from passion fruit peel for methylene blue dye removal
The adsorption of methylene blue (MB) dye onto passion fruit peel based activated carbon (PFPAC) was investigated in a batch study. Passion fruit peel undergoes physical activation process which involves microwave irradiation and carbon dioxide gasification to prepare PFPAC. The optimum preparation conditions were obtained from response surface methodology (RSM) at radiation power and activation time of 616 W and 6.24 minutes, respectively which resulted in 85.66% MB removal and 39.9% PFPAC yield. Optimized PFPAC has high surface area, pore volume and fixed carbon content and average pore diameter of 782.3 m2/g, 0.422 cm3/g and 0.295 nm, respectively. Freundlich isotherm model fitted well the adsorption equilibrium data. The adsorption kinetic was found to follow the pseudo-second-order kinetic model.The adsorption of methylene blue (MB) dye onto passion fruit peel based activated carbon (PFPAC) was investigated in a batch study. Passion fruit peel undergoes physical activation process which involves microwave irradiation and carbon dioxide gasification to prepare PFPAC. The optimum preparation conditions were obtained from response surface methodology (RSM) at radiation power and activation time of 616 W and 6.24 minutes, respectively which resulted in 85.66% MB removal and 39.9% PFPAC yield. Optimized PFPAC has high surface area, pore volume and fixed carbon content and average pore diameter of 782.3 m2/g, 0.422 cm3/g and 0.295 nm, respectively. Freundlich isotherm model fitted well the adsorption equilibrium data. The adsorption kinetic was found to follow the pseudo-second-order kinetic model.
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