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6TH INTERNATIONAL CONFERENCE ON ENVIRONMENT (ICENV2018): Empowering Environment and Sustainable Engineering Nexus Through Green Technology最新文献

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Recent development in the electrochemical conversion of carbon dioxide: Short review 二氧化碳电化学转化研究进展综述
F. Hussin, M. Aroua
Carbon dioxide (CO2) release from the burning of fossil fuels such as oil, coal and natural gas are contributing to the increase in the greenhouse gas (GHG) levels in the atmosphere. Most countries and scientific research communities are endeavoring to solve the climate change issue due to global warming by reducing GHG emissions. At present, most of the researches are focusing on decreasing the dependency on fossil fuels and replacing them with renewable energy. Nevertheless, this transition still faced major obstacles such as require new infrastructure, technology and market failures. To solve this problem, three CO2 emission reduction strategies can be used, namely CO2 capture and storage (CCS), CO2 utilisation and CO2 conversion. Among these potential approaches, the utilisation and conversion of CO2 are preferable since it converts harmful gas into valuable products. Moreover, conversion of CO2 is a key element for sustainable development towards the low-carbon economy. Furthermore, the application of carbon dioxide conversion technologies involves CO2 capture and reprocess would able to stabilise the atmospheric GHG levels and make a good prospect to transform CO2 into value-added products. A recent advance in electrochemical CO2 conversion has opened an existing possibility of utilisation of CO2 as useful for fuel generation and produce a valuable commodity chemical. This short review highlights the current development related to an electrochemical conversion of CO2 between 2014 and 2018. In addition, this review discusses recent technologies and approaches through electrochemical reduction using electrocatalyst and biocatalyst. This review also aims in providing the research community with current research in this electrochemical field also inspiring new ideas in the CO2 electrochemical conversion technology.
燃烧石油、煤炭和天然气等化石燃料释放的二氧化碳(CO2)正在导致大气中温室气体(GHG)水平的增加。大多数国家和科学界都在努力通过减少温室气体排放来解决全球变暖带来的气候变化问题。目前,大多数研究都集中在减少对化石燃料的依赖,用可再生能源替代化石燃料上。然而,这一转变仍然面临重大障碍,如需要新的基础设施、技术和市场失灵。为了解决这一问题,可以采用三种二氧化碳减排策略,即二氧化碳捕集与封存(CCS)、二氧化碳利用和二氧化碳转化。在这些可能的方法中,利用和转化二氧化碳是可取的,因为它将有害气体转化为有价值的产品。此外,二氧化碳的转化是向低碳经济可持续发展的关键因素。此外,二氧化碳转化技术的应用涉及二氧化碳捕获和后处理,可以稳定大气温室气体水平,并为将二氧化碳转化为增值产品提供了良好的前景。最近在电化学CO2转化方面取得的进展使现有的利用CO2作为有用的燃料产生和生产有价值的商品化学品的可能性成为可能。这篇简短的综述重点介绍了2014年至2018年期间与二氧化碳电化学转化相关的当前发展。此外,本文还对电催化剂和生物催化剂的电化学还原技术和方法进行了综述。本文旨在为研究人员提供这一电化学领域的最新研究进展,并为二氧化碳电化学转化技术的研究提供新的思路。
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引用次数: 8
Flow regime analysis of Taylor-Couette column for emulsion liquid membrane applications Taylor-Couette色谱柱在乳化液膜中的流态分析
A. Kusumastuti, Gunawan Muhammad Najibulloh, N. Qudus, S. Anis
Study on the application of Taylor-Couette column for emulsion liquid membrane system has been done. To optimise extraction process under TCC, a research to investigate effect of volume ratio of oil to water is of important. Fluid viscosity was examined by varying volume ratio of kerosene to water. TCC was characterised to determine flow regimes, shear stress, and energy loss distribution. Volume ratio of oil to water was varied at 1:1, 1:3, 1:5, and 1:6 while inner and outer cylinders speed were maintained constant at 31.4 and 0 rad/s, respectively. Investigation on the effect of volume ratio of oil to water towards flow regime ended to same flow regime of Turbulence Taylor Vortices (TTV). There was degradation of wall shear stress from 8.57x10−2 Pa to 7.42x10−2 Pa.Study on the application of Taylor-Couette column for emulsion liquid membrane system has been done. To optimise extraction process under TCC, a research to investigate effect of volume ratio of oil to water is of important. Fluid viscosity was examined by varying volume ratio of kerosene to water. TCC was characterised to determine flow regimes, shear stress, and energy loss distribution. Volume ratio of oil to water was varied at 1:1, 1:3, 1:5, and 1:6 while inner and outer cylinders speed were maintained constant at 31.4 and 0 rad/s, respectively. Investigation on the effect of volume ratio of oil to water towards flow regime ended to same flow regime of Turbulence Taylor Vortices (TTV). There was degradation of wall shear stress from 8.57x10−2 Pa to 7.42x10−2 Pa.
对Taylor-Couette色谱柱在乳化液膜体系中的应用进行了研究。为了优化TCC条件下的萃取工艺,研究油水体积比的影响是十分重要的。通过改变煤油与水的体积比来测定流体粘度。对TCC进行表征,以确定流动形式、剪切应力和能量损失分布。油水体积比分别为1:1、1:3、1:5和1:6,内缸和外缸转速分别为31.4和0 rad/s。研究了油水体积比对湍流泰勒涡(TTV)相同流型的影响。墙体剪应力从8.57x10−2 Pa降至7.42x10−2 Pa。对Taylor-Couette色谱柱在乳化液膜体系中的应用进行了研究。为了优化TCC条件下的萃取工艺,研究油水体积比的影响是十分重要的。通过改变煤油与水的体积比来测定流体粘度。对TCC进行表征,以确定流动形式、剪切应力和能量损失分布。油水体积比分别为1:1、1:3、1:5和1:6,内缸和外缸转速分别为31.4和0 rad/s。研究了油水体积比对湍流泰勒涡(TTV)相同流型的影响。墙体剪应力从8.57x10−2 Pa降至7.42x10−2 Pa。
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引用次数: 1
Earthworms as plug flow reactors: An enzyme deactivation kinetic study along the gut of the earthworm Eudrilus eugeniae 蚯蚓作为塞流反应器:沿原生蚯蚓肠道酶失活动力学研究
K. Kiyasudeen, F. N. Gonawan, M. Ibrahim, S. A. Ismail, S. A. Muhammad
Several researchers have modeled animal’s guts as reactors, although not many discuss earthworm specifically. The present study applies plug flow reactor (PFR) based enzyme deactivation kinetic model by using three deactivation rates (β), i.e., 0.05, 0.1 and 0.15 to predict the changes in proteolytic activity, profile of crude protein and amino acids at five distinct sections, i.e., pre-intestine, foregut, midgut A, midgut B, and Hindgut along the gut of the earthworm Eudrilus eugeniae. At three rates of deactivation, three different range of reduction in proteolytic activity was predicted, i.e., (i) 52.28% decrease when β-value was set at 0.05, (ii) 77.23% decrease when β-value was set at 0.1, and (iii) 93.03% decrease when β-value was set at 0.15. In the case of crude protein, the concentration decreased along the gut for all the three β-values at the level of 31.21%, 49.28% and 66.90%, when β value was set at 0.05, 0.1 and 0.15 respectively. The effect of deactivation on amino acids also revealed a pattern steady decrease, i.e., 93.83%, 96.85% and 98.87% decrease when β was set at 0.05, 0.1 and 0.15.Several researchers have modeled animal’s guts as reactors, although not many discuss earthworm specifically. The present study applies plug flow reactor (PFR) based enzyme deactivation kinetic model by using three deactivation rates (β), i.e., 0.05, 0.1 and 0.15 to predict the changes in proteolytic activity, profile of crude protein and amino acids at five distinct sections, i.e., pre-intestine, foregut, midgut A, midgut B, and Hindgut along the gut of the earthworm Eudrilus eugeniae. At three rates of deactivation, three different range of reduction in proteolytic activity was predicted, i.e., (i) 52.28% decrease when β-value was set at 0.05, (ii) 77.23% decrease when β-value was set at 0.1, and (iii) 93.03% decrease when β-value was set at 0.15. In the case of crude protein, the concentration decreased along the gut for all the three β-values at the level of 31.21%, 49.28% and 66.90%, when β value was set at 0.05, 0.1 and 0.15 respectively. The effect of deactivation on amino acids also revealed a pat...
一些研究人员已经将动物的内脏作为反应器进行建模,尽管没有多少人专门讨论蚯蚓。本研究采用塞流反应器(PFR)为基础的酶失活动力学模型,采用3种失活率(β),分别为0.05、0.1和0.15,预测了eugenae蚯蚓肠前、前肠、中肠A、中肠B和后肠5个不同部位的蛋白水解活性、粗蛋白质和氨基酸谱的变化。在三种失活速率下,预测了三种不同的蛋白水解活性降低幅度,即(i) β值为0.05时降低52.28%,(ii) β值为0.1时降低77.23%,(iii) β值为0.15时降低93.03%。以粗蛋白质为例,当β值分别为0.05、0.1和0.15时,3种β值沿肠道的浓度均降低,分别为31.21%、49.28%和66.90%。当β为0.05、0.1和0.15时,失活对氨基酸的影响也呈稳定下降的趋势,分别下降了93.83%、96.85%和98.87%。一些研究人员已经将动物的内脏作为反应器进行建模,尽管没有多少人专门讨论蚯蚓。本研究采用塞流反应器(PFR)为基础的酶失活动力学模型,采用3种失活率(β),分别为0.05、0.1和0.15,预测了eugenae蚯蚓肠前、前肠、中肠A、中肠B和后肠5个不同部位的蛋白水解活性、粗蛋白质和氨基酸谱的变化。在三种失活速率下,预测了三种不同的蛋白水解活性降低幅度,即(i) β值为0.05时降低52.28%,(ii) β值为0.1时降低77.23%,(iii) β值为0.15时降低93.03%。以粗蛋白质为例,当β值分别为0.05、0.1和0.15时,3种β值沿肠道的浓度均降低,分别为31.21%、49.28%和66.90%。失活对氨基酸的影响也揭示了部分…
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引用次数: 0
Optimizing purity and recovery of hydrogen from syngas by equalized pressure swing adsorption using palm kernel shell activated carbon adsorbent 棕榈仁壳活性炭等变压吸附法优化合成气中氢的纯度和回收率
I. Idris, A. Abdullah, I. Shamsudin, M. Othman
This paper provides with a first assessment on the sustainability of Pressure Swing Adsorption (PSA) as a valid option for Carbon Dioxide (CO2) capture in power plant. PSA is a well-established gas...
本文首次评估了变压吸附(PSA)作为发电厂二氧化碳捕集的有效选择的可持续性。PSA是一种成熟的气体…
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引用次数: 5
Fabrication and optimization of immobilized bentonite and TiO2 photocatalyst in unilayer and bilayer system for the photocatalytic adsorptive removal of methylene blue dye under UV light 固定化膨润土和TiO2光催化剂单层和双层体系的制备及优化,用于紫外光下光催化吸附去除亚甲基蓝染料
M. Mahmood, S. Ismail
A highly effective and reusable immobilized unilayer thin coating of bentonite and photocatalyst was fabricated on the glass beaker to remove aqueous methylene blue solution. It was observed that t...
在玻璃烧杯上制备了一种高效、可重复使用的膨润土和光催化剂单层固定膜,用于去除亚甲基蓝水溶液。据观察,……
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引用次数: 2
Optimization of ionic liquid-based microwave extraction of flavonoid and phenolic acid from Labisia Pumila 离子液体微波提取阴唇黄酮和酚酸的工艺优化
N. A. Rahman, Ani Idris, N. Yunus, A. Mustaffa
Ionic liquids have attracted many researches in bioactive compound separation as well as carbon capture. This is due to the ability of ionic liquid to be designed based on specific needs and produc...
离子液体在生物活性化合物分离和碳捕获等方面引起了广泛的研究。这是由于离子液体能够根据特定需求和产品进行设计。
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引用次数: 5
Effect of chitosan modification on PAN/nanosilica adsorptive membrane for quercetin filtration 壳聚糖改性对PAN/纳米二氧化硅吸附膜过滤槲皮素的影响
N. M. Nor, S. A. Hamid, M. S. Shamsudin, S. Ismail
Quercetin is a plant pigment from flavonoid group found in many plants and foods such as onions, green tea, apples and berries and can be taken as health supplements to support heart issues and prevent cancer due to the function of antioxidant and anti-inflammatory effects. Basically, quercetin can be easily separated from water sources when it is operated with nanofiltration (NF) and reverse osmosis (RO) mode since the pore size of membrane is very small. However, these processes generally require high operating pressure during treatment process, resulting in significant energy consumption. Thus, an adsorptive membrane is fabricated with microfiltration (MF) range combining polyacrylonitrile (PAN) and nanosilica as the adsorbent to adsorb quercetin on the membrane with lower pressure in the operation. This paper is focused on modification of PAN/Nanosilica adsorptive membrane with chitosan to improve the performance flux and quercetin adsorption varying two membrane modification methods which are chitosan coating and chitosan blending. The adsorptive membrane fabricated using PAN/Nanosilica modified by chitosan coating is found as the best membrane for quercetin filtration compared to PAN/Nanosilica membrane modified by chitosan blending because higher initial flux for pure water and quercetin were achieved and flux reduction for quercetin using PAN/Nanosilica/Chitosan coated membrane is the lowest which is 57.5%.
槲皮素是一种黄酮类植物色素,存在于许多植物和食物中,如洋葱、绿茶、苹果和浆果。槲皮素具有抗氧化和抗炎作用,可以作为健康补充剂来治疗心脏病和预防癌症。由于膜的孔径很小,采用纳滤(NF)和反渗透(RO)方式,基本上可以很容易地从水源中分离槲皮素。然而,这些工艺在处理过程中通常需要较高的操作压力,导致大量的能源消耗。因此,采用微滤(MF)范围结合聚丙烯腈(PAN)和纳米二氧化硅作为吸附剂,制备了一种吸附膜,在操作过程中以较低的压力将槲皮素吸附在膜上。研究了壳聚糖对聚丙烯腈/纳米二氧化硅吸附膜的改性,通过壳聚糖包覆和壳聚糖共混两种膜改性方法,提高了聚丙烯腈/纳米二氧化硅吸附膜的性能通量和槲皮素吸附性能。经壳聚糖包覆改性PAN/纳米二氧化硅制备的吸附膜比壳聚糖共混改性PAN/纳米二氧化硅膜过滤槲皮素的效果更好,因为PAN/纳米二氧化硅/壳聚糖包覆膜对纯水和槲皮素的初始通量更高,对槲皮素的通量降低最低,为57.5%。
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引用次数: 0
A short review: Potential use of plastic waste as adsorbent for various pollutants 综述:塑料废物作为各种污染物吸附剂的潜在用途
N. Abd-Aziz, S. Alias, N. M. Bashar, A. Amir, S. Abdul-Talib, C. C. Tay
This paper reviews on the performance of different plastic waste as value-added adsorbent under different environmental pollution. As adsorbent, it should tender the uppermost rates of pollutant removal, cost-effective and easy to obtain. The first part of this paper discussed on the concept of adsorption process. Since adsorbents assortment is the key for adsorption study, the adsorption of dissimilar types of pollutants by different kind of plastic waste as an adsorbent are then reviewed in the following part. The use of different plastic waste of various types includes plastic carrier bag, coffee cup, plastic container and food packaging which are made from polystyrene, polypropylene, polyethylene terephthalate, high-density polyethylene, polyvinyl chloride and low-density polyethylene are highlighted in this paper. The advantageous of each plastic waste as adsorbent are discussed. It was found that they possess most excellent performance on the potential adsorption of pollutants in various environmental pollutants. It is believed that using of plastic waste not only provides a novel potential way to utilize waste plastics, but also put forward a facile sustainable approach in remediating environment pollution.This paper reviews on the performance of different plastic waste as value-added adsorbent under different environmental pollution. As adsorbent, it should tender the uppermost rates of pollutant removal, cost-effective and easy to obtain. The first part of this paper discussed on the concept of adsorption process. Since adsorbents assortment is the key for adsorption study, the adsorption of dissimilar types of pollutants by different kind of plastic waste as an adsorbent are then reviewed in the following part. The use of different plastic waste of various types includes plastic carrier bag, coffee cup, plastic container and food packaging which are made from polystyrene, polypropylene, polyethylene terephthalate, high-density polyethylene, polyvinyl chloride and low-density polyethylene are highlighted in this paper. The advantageous of each plastic waste as adsorbent are discussed. It was found that they possess most excellent performance on the potential adsorption of pollutants in various environment...
本文综述了不同塑料废弃物在不同环境污染下作为增值吸附剂的性能。作为吸附剂,它应具有最高的污染物去除率,性价比高,易于获得。本文第一部分讨论了吸附过程的概念。由于吸附剂的分类是吸附研究的关键,下面就不同种类的塑料废物作为吸附剂对不同类型污染物的吸附进行了综述。本文重点介绍了聚苯乙烯、聚丙烯、聚对苯二甲酸乙二醇酯、高密度聚乙烯、聚氯乙烯和低密度聚乙烯等不同类型塑料废弃物的利用,包括塑料手提袋、咖啡杯、塑料容器和食品包装。讨论了各种塑料废弃物作为吸附剂的优点。发现它们在各种环境污染物中对潜在污染物的吸附性能最为优异。塑料废弃物资源化利用不仅为废塑料的资源化利用提供了一条新的、有潜力的途径,而且为环境污染的治理提供了一条便捷的可持续途径。本文综述了不同塑料废弃物在不同环境污染下作为增值吸附剂的性能。作为吸附剂,它应具有最高的污染物去除率,性价比高,易于获得。本文第一部分讨论了吸附过程的概念。由于吸附剂的分类是吸附研究的关键,下面就不同种类的塑料废物作为吸附剂对不同类型污染物的吸附进行了综述。本文重点介绍了聚苯乙烯、聚丙烯、聚对苯二甲酸乙二醇酯、高密度聚乙烯、聚氯乙烯和低密度聚乙烯等不同类型塑料废弃物的利用,包括塑料手提袋、咖啡杯、塑料容器和食品包装。讨论了各种塑料废弃物作为吸附剂的优点。结果表明,它们在各种环境中对污染物的潜在吸附性能都非常优异。
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引用次数: 10
Activation of persulphate by heat, pH, and transition metals for removal of COD and colour from biologically treated palm oil mill effluent 用热、pH值和过渡金属活化过硫酸盐去除经生物处理的棕榈油厂废水中的COD和颜色
Tay Huat Hua, A. C. Affam, W. C. Chung, Wong Chee Swee, J. Adebayo
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引用次数: 1
Enhancement of the activated carbon over methylene blue removal efficiency via alkali-acid treatment 碱-酸处理提高活性炭对亚甲基蓝的去除效率
N. Saafie, Mohamad Fakhrul Ridhwan Samsudin, S. Sufian, R. Ramli
The removal of contaminated dyes in wastewater via Activated Carbon (AC) technology is a promising alternative to current conventional pollution-free technologies. Herein, the commercial AC with enhanced adsorption performance capacity were comprehensively investigated via modulating with the alkali-acid treatment. The removal of a highly concentrated methylene blue solution was evaluated via a commercial AC treated with deionized water (AC-DI), potassium hydroxide (AC-KOH) and nitric acid (AC-HNO3). The physicochemical properties of the modified AC were characterized using Fourier Transform Infra-Red (FTIR), X-ray Diffraction (XRD), Field Emission Scanning Electron Microscope (FESEM) and Surface area analyzer and Porosity analysis (SAP). The AC modified with deionized water (AC-DI) exhibited superior adsorption performance with 99% of methylene blue removal within 8 hours. Gratifyingly, the AC-DI has the fastest adsorption uptake within 2 hours in comparison to AC, AC-KOH and AC-HNO3 samples. The superior methylene blue removal performance of AC-DI was attributed to the enhanced surface group functionalization over the surface of AC evidenced from the FTIR analysis. In addition, the better crystallinity of AC-DI sample as shown in XRD and FESEM micrograph analysis does help to improve the adsorption of contaminated dye molecules onto the surface complex of AC, results in a superior rate of methylene blue removal. These results suggest that the alkali-acid treatment shows promises in enhancing the adsorption rate capabilities of commercial AC for the removal of basic dyes from wastewater.The removal of contaminated dyes in wastewater via Activated Carbon (AC) technology is a promising alternative to current conventional pollution-free technologies. Herein, the commercial AC with enhanced adsorption performance capacity were comprehensively investigated via modulating with the alkali-acid treatment. The removal of a highly concentrated methylene blue solution was evaluated via a commercial AC treated with deionized water (AC-DI), potassium hydroxide (AC-KOH) and nitric acid (AC-HNO3). The physicochemical properties of the modified AC were characterized using Fourier Transform Infra-Red (FTIR), X-ray Diffraction (XRD), Field Emission Scanning Electron Microscope (FESEM) and Surface area analyzer and Porosity analysis (SAP). The AC modified with deionized water (AC-DI) exhibited superior adsorption performance with 99% of methylene blue removal within 8 hours. Gratifyingly, the AC-DI has the fastest adsorption uptake within 2 hours in comparison to AC, AC-KOH and AC-HNO3 samples. The superio...
活性炭(AC)技术对废水中受污染染料的去除是目前传统无公害技术的一种很有前景的替代技术。在此基础上,通过碱-酸处理的调制,全面研究了具有增强吸附性能的商用活性炭。用去离子水(AC- di)、氢氧化钾(AC- koh)和硝酸(AC- hno3)处理的商用AC对高浓度亚甲基蓝溶液的去除率进行了研究。采用傅里叶变换红外(FTIR)、x射线衍射(XRD)、场发射扫描电镜(FESEM)和表面积分析仪及孔隙度分析(SAP)对改性AC的理化性质进行了表征。用去离子水(AC- di)改性的AC具有优异的吸附性能,8小时内亚甲基蓝去除率达99%。令人欣慰的是,与AC、AC- koh和AC- hno3样品相比,AC- di在2小时内的吸附速度最快。AC- di具有优异的亚甲基蓝脱除性能,主要归因于AC表面基功能化的增强。此外,XRD和FESEM显微图分析表明AC- di样品的结晶度较好,有助于改善污染染料分子在AC表面配合物上的吸附,从而获得较好的亚甲基蓝去除率。这些结果表明,碱-酸处理有望提高工业活性炭对废水中碱性染料的吸附率。活性炭(AC)技术对废水中受污染染料的去除是目前传统无公害技术的一种很有前景的替代技术。在此基础上,通过碱-酸处理的调制,全面研究了具有增强吸附性能的商用活性炭。用去离子水(AC- di)、氢氧化钾(AC- koh)和硝酸(AC- hno3)处理的商用AC对高浓度亚甲基蓝溶液的去除率进行了研究。采用傅里叶变换红外(FTIR)、x射线衍射(XRD)、场发射扫描电镜(FESEM)和表面积分析仪及孔隙度分析(SAP)对改性AC的理化性质进行了表征。用去离子水(AC- di)改性的AC具有优异的吸附性能,8小时内亚甲基蓝去除率达99%。令人欣慰的是,与AC、AC- koh和AC- hno3样品相比,AC- di在2小时内的吸附速度最快。superio……
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引用次数: 10
期刊
6TH INTERNATIONAL CONFERENCE ON ENVIRONMENT (ICENV2018): Empowering Environment and Sustainable Engineering Nexus Through Green Technology
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