伊拉克纳希里亚市幼发拉底河中内分泌干扰物生物浓度的估计

Murooj abbas buhlool
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摘要

水中的内分泌干扰物(EDCs)因其对生物的潜在不良影响而受到全世界的关注。本研究的目的是研究伊拉克Al-Nassiryia市幼发拉底河的内分泌干扰因素。2016年秋冬两季采集各地点样品,采用固相法提取,HPLC-UV分析,乙烯基雌二醇波长为210 nm,其他化合物波长为280 nm。结果表明,双酚A含量为0.001 ~ 0.98 μg/L,壬基酚含量为0.09 ~ 5.7 μg/L, 17-雌二醇含量为2.05 ~ 19.9 ng/L。雌二醇含量为0.1 ~ 54 ng/L,乙炔雌二醇含量为0.91 ~ 6.2 ng/L。st.2的污染物浓度水平高于st.1和st.3。水体分析表明,st.2秋季污染物浓度水平高于冬季(p值≤0.005),这可能与环境条件的变化有关。广泛使用含有这些强效雌激素化学物质的避孕药似乎是释放雌激素化合物进入水生环境的更重要途径。
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ESTIMATE OF BIOCONCENTRATION OF ENDOCRINE DISRUPTING CHEMICALS IN EUPHRATES RIVER IN Al-NASSIRYIA CITY OF IRAQ
Endocrine disrupting chemicals (EDCs) in water  have been of  overworld  concern due to their potential adverse effects in organisms . The objective of this study was to examine endocrine-disrupting factors in Euphrates river , in Al-Nassiryia city/Iraq.    Samples from all locations were collected during autumn2016 and winter2016, extracted by solid phase method and analyzed by HPLC-UV in the wave length of  210 nm for ethinyl estradiol and 280 nm for other compounds. The results showed that presence of bisphenol A with concentrations ranging 0.001 to 0.98 μg/L and   0.09 – 5.7 μg/L nonylphenol and  2.05 – 19.9 ng/L for 17-beta estradiol. Estron was 0.1 to 54 ng/L  and 0.91-6.2 ng/L for ethinyl estradiol.       The concentration levels of pollutants in st.2 were  higher than the st.1 and st.3. Analysis of water showed that concentration levels of pollutants were higher during autumn comparing with winter in st.2 (Pvalue ≤0.005), which may be due to the changes of environmental conditions.      The widespread use of birth control pills formulated with these content of potent estrogenic chemicals appear to be the more important path for the freeing of estrogenic compounds into the aquatic environment.
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