AIC多晶硅种子层晶粒扩大的取向选择外延

Sung-Yen Wei, Sheng-min Yu, Hung-Hsi Lin, Wei Chen, Chun-Jen Chen, Tzer-Shen Lin, C. Tsai, Fu-Rong Chen
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摘要

提出了一种利用铝诱导多轮结晶(AIC)在玻璃表面制备高(100)取向大晶粒多晶硅种子层的新方法。首先采用常规AIC工艺制备了一层200nm的平面多晶硅层作为基层。在基层上立即进行第二轮AIC工艺,通过固相外延(SPE)机制外延长成400nm的多晶硅层。利用透射电子显微镜(TEM)对扩大后的外延晶粒结构进行了观察,利用电子背散射衍射(EBSD)对晶粒进行了取向图和大面积尺寸直方图的绘制,并利用拉曼光谱法对多轮AIC的结晶度进行了验证。横截面透射电镜分析可以清楚地观察到横向生长和晶粒抑制。通过对直方图的分析,可以确定平均粒度。生长平面的取向对外延生长的速度有很大影响。我们利用这一特性,提高{100}的比例,减少其他比例,为接下来的加厚步骤获得高度定向的种层。{100}晶体平面的居群由取向图和极图分析统计得到。会议将详细讨论多轮对话机制。
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Orientation selected epitaxy for grain enlargement of AIC poly-Si seed layers
A novel method for producing a highly-(100) orientated, large grain of poly-Si seed layer on glass by multi-round aluminum-induced crystallization (AIC) is developed. A flat 200nm poly-Si layer was first fabricated by regular AIC process to be a based layer. The second round AIC process was carried out immediately on the based layer to epitaxially grow up to a 400nm poly-Si layer by solid phase epitaxy (SPE) mechanism. The structure of enlarged epitaxial grain was examined by transmission electron microscopy (TEM), the orientation map as well as histogram of grain size from large area were performed by electron backscatter diffraction (EBSD), and the crystallinity of multi-round AIC was verified by Raman spectrometry. The lateral growth and grain suppression can be clearly observed in cross-sectional TEM analysis. The average grain size can be determined from analysis of histogram. The speed of epitaxial growth is strongly influenced by the orientation of the growth plane. We utilize this characteristic to promote the {100} proportion and reduce others to achieve a highly oriented seed-layer for followed thickening step. The population of {100} crystallographic plane is obtained statistically from orientation map and a pole figure analysis. The mechanism of the multi-round AIC will be discussed in detail in the conference.
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