{"title":"313k超声技术对正己烷溶液中1-戊醇与某些有机化合物三元体系的过量性能及理论评价","authors":"P. S. S. Ibrahim, J. Jeyakumar, S. Vinayagam","doi":"10.6000/1929-5030.2021.10.01","DOIUrl":null,"url":null,"abstract":": The parameters like density( ρ ), ultrasonic velocity (U), and viscosity ( η ) were experimentally measured. The excess parameters like adiabatic compressibility, acoustic impedance, free volume, free length, internal pressure and ultrasonic velocity in addition to K value were computed from the experimental data. The variation of these parameters at a constant temperature for the three ternary systems, namely OMP + 1-pentanol+n-hexane, N, N-DMF + 1-pentanol+n-hexane, and MMP + 1-pentanol+n-hexane, have been discussed in the light of molecular interaction. Further, certain theoretical studies are validated with respect to experimental velocities, and the Chi-square test for the goodness of fit is also applied to check the validity of such theoretical models.","PeriodicalId":15165,"journal":{"name":"Journal of Applied Solution Chemistry and Modeling","volume":"55 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Excess Properties and Theoretical Evaluation on Ternary Systems of 1-Pentanol in n-Hexane Solution with some Organic Compounds at 313 K Using Ultrasonic Technique\",\"authors\":\"P. S. S. Ibrahim, J. Jeyakumar, S. Vinayagam\",\"doi\":\"10.6000/1929-5030.2021.10.01\",\"DOIUrl\":null,\"url\":null,\"abstract\":\": The parameters like density( ρ ), ultrasonic velocity (U), and viscosity ( η ) were experimentally measured. The excess parameters like adiabatic compressibility, acoustic impedance, free volume, free length, internal pressure and ultrasonic velocity in addition to K value were computed from the experimental data. The variation of these parameters at a constant temperature for the three ternary systems, namely OMP + 1-pentanol+n-hexane, N, N-DMF + 1-pentanol+n-hexane, and MMP + 1-pentanol+n-hexane, have been discussed in the light of molecular interaction. Further, certain theoretical studies are validated with respect to experimental velocities, and the Chi-square test for the goodness of fit is also applied to check the validity of such theoretical models.\",\"PeriodicalId\":15165,\"journal\":{\"name\":\"Journal of Applied Solution Chemistry and Modeling\",\"volume\":\"55 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-04-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Solution Chemistry and Modeling\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.6000/1929-5030.2021.10.01\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Solution Chemistry and Modeling","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.6000/1929-5030.2021.10.01","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Excess Properties and Theoretical Evaluation on Ternary Systems of 1-Pentanol in n-Hexane Solution with some Organic Compounds at 313 K Using Ultrasonic Technique
: The parameters like density( ρ ), ultrasonic velocity (U), and viscosity ( η ) were experimentally measured. The excess parameters like adiabatic compressibility, acoustic impedance, free volume, free length, internal pressure and ultrasonic velocity in addition to K value were computed from the experimental data. The variation of these parameters at a constant temperature for the three ternary systems, namely OMP + 1-pentanol+n-hexane, N, N-DMF + 1-pentanol+n-hexane, and MMP + 1-pentanol+n-hexane, have been discussed in the light of molecular interaction. Further, certain theoretical studies are validated with respect to experimental velocities, and the Chi-square test for the goodness of fit is also applied to check the validity of such theoretical models.