CuSbSe2 - CuInSe2体系的制备及相关系

B. Korzun, V. Sobol', M. Rusu, Ruben M. Savizky, A. A. Fadzeyeva, I. I. Maroz, A. N. Gavrilenko, V. Matukhin, M. Lux‐Steiner
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引用次数: 1

摘要

制备了CuInSe2 (x)摩尔分数分别为0.05、0.15、0.25、0.375、0.50、0.625、0.75、0.85和0.95的(CuSbSe2)1-x⋅(CuInSe2)x体系CuInSe2和CuSbSe2三元化合物和合金,并用x射线粉末衍射、光学显微镜和扫描电镜研究了该体系的相关系。结果表明,CuSbSe2-CuInSe2体系的合金在整个组成范围内均为室温双相,CuSbSe2在CuInSe2中的溶解度极限和CuSbSe2在CuSbSe2中的溶解度极限均不超过0.001摩尔分数。
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Preparation and Phase Relations in the CuSbSe2 – CuInSe2 System
The CuInSe2 and CuSbSe2 ternary compounds and alloys of the (CuSbSe2)1-x⋅(CuInSe2)x system with the mole fraction of CuInSe2 (x) equal to 0.05, 0.15, 0.25, 0.375, 0.50, 0.625, 0.75, 0.85, and 0.95 were prepared and the phase relations in this system were investigated by X-ray powder diffraction, optical microscopy, and scanning electron microscopy. It was shown that the alloys of the CuSbSe2-CuInSe2 system are biphasic at room temperature in the whole range of compositions, and the limits of solubility for CuSbSe2 in CuInSe2 and for CuInSe2 in CuSbSe2 do not exceed 0.001 mole fraction.
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