{"title":"用N, N ' -双(2-羟基苄基氨基)苯金(III)配合物非酶促葡萄糖氧化制葡萄糖酸","authors":"Sontara Konwar Boruah, Hirendra Das, Prabin Kumar Boruah","doi":"10.1007/s12039-023-02198-7","DOIUrl":null,"url":null,"abstract":"<div><p>In this paper we report non-enzymatic glucose oxidation with N, N′-Bis(2-hydroxybenzylidineamino) benzene gold (III) complex on reduced graphene oxide-gold (rGO-Au) nanoparticle coated modified copper (Cu) electrode. Potassium ferricyanide in 50 mM phosphate buffer solution (pH 7.0) was used as a mediator. The [(Salophen)Au]<sup>+</sup> on rGO shows good catalytic property for the oxidation of glucose to gluconic acid (GA). The maximum current response produced by Au<sup>3+</sup>/Au<sup>+</sup> redox potential was monitored by the linear sweep voltammetric method (LSV). As glucose concentration increases the current response at Au<sup>+3</sup>/Au<sup>+</sup> redox potential decreases simultaneously. On catalytic oxidation of glucose to GA by the complex [(Salophen)Au]<sup><b>+</b></sup>, the solution pH reduces to 2.75, which results the decrease of current responses at the Au<sup>3+</sup>/Au<sup>+</sup> working potential.</p><h3>Graphical abstract</h3><p>Direct oxidation of glucose to gluconic acid is achieved adopting nonenzytnatic technique by rGO based heterogeneous catalyst is reported in the present study. N,N'-Bis (2-hydroxy benzylidineatnino) benzene gold (III) complex on rGO-Au nanoparticles is used to fabricate the tnodified electrode. The oxidation mechanism is demonstrated. This work showed the potential of using [(Salophen)Au]<sup>+</sup> Schiff base complex as a nonenzymatic substitute for glucose oxidize enzyme.\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":616,"journal":{"name":"Journal of Chemical Sciences","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2023-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Non-enzymatic glucose oxidation to gluconic acid with N, N′-bis(2-hydroxybenzylidineamino) benzene gold (III) complex\",\"authors\":\"Sontara Konwar Boruah, Hirendra Das, Prabin Kumar Boruah\",\"doi\":\"10.1007/s12039-023-02198-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this paper we report non-enzymatic glucose oxidation with N, N′-Bis(2-hydroxybenzylidineamino) benzene gold (III) complex on reduced graphene oxide-gold (rGO-Au) nanoparticle coated modified copper (Cu) electrode. Potassium ferricyanide in 50 mM phosphate buffer solution (pH 7.0) was used as a mediator. The [(Salophen)Au]<sup>+</sup> on rGO shows good catalytic property for the oxidation of glucose to gluconic acid (GA). The maximum current response produced by Au<sup>3+</sup>/Au<sup>+</sup> redox potential was monitored by the linear sweep voltammetric method (LSV). As glucose concentration increases the current response at Au<sup>+3</sup>/Au<sup>+</sup> redox potential decreases simultaneously. On catalytic oxidation of glucose to GA by the complex [(Salophen)Au]<sup><b>+</b></sup>, the solution pH reduces to 2.75, which results the decrease of current responses at the Au<sup>3+</sup>/Au<sup>+</sup> working potential.</p><h3>Graphical abstract</h3><p>Direct oxidation of glucose to gluconic acid is achieved adopting nonenzytnatic technique by rGO based heterogeneous catalyst is reported in the present study. N,N'-Bis (2-hydroxy benzylidineatnino) benzene gold (III) complex on rGO-Au nanoparticles is used to fabricate the tnodified electrode. The oxidation mechanism is demonstrated. This work showed the potential of using [(Salophen)Au]<sup>+</sup> Schiff base complex as a nonenzymatic substitute for glucose oxidize enzyme.\\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":616,\"journal\":{\"name\":\"Journal of Chemical Sciences\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2023-07-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Sciences\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12039-023-02198-7\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Sciences","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s12039-023-02198-7","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
在本文中,我们报道了N, N ' -双(2-羟基苄基氨基)苯金(III)配合物在还原氧化石墨烯-金(rGO-Au)纳米颗粒包覆的修饰铜(Cu)电极上非酶氧化葡萄糖。采用50 mM磷酸盐缓冲液(pH 7.0)中的铁氰化钾作为介质。还原氧化石墨烯上的[(Salophen)Au]+对葡萄糖氧化制葡萄糖酸(GA)具有良好的催化性能。采用线性扫描伏安法(LSV)监测了Au3+/Au+氧化还原电位产生的最大电流响应。随着葡萄糖浓度的增加,Au+3/Au+氧化还原电位的电流响应同时降低。配合物[(Salophen)Au]+催化葡萄糖氧化制GA时,溶液pH降至2.75,导致在Au3+/Au+工作电位处电流响应降低。摘要本文报道了采用非酶催化技术,以氧化石墨烯为基础的多相催化剂,实现了葡萄糖直接氧化制葡萄糖酸。采用N,N'-双(2-羟基苄基苯基尼诺)苯金(III)配合物在氧化石墨烯-金纳米颗粒上制备二甲基化电极。证明了氧化机理。本研究显示了[(Salophen)Au]+希夫碱配合物作为葡萄糖氧化酶的非酶替代品的潜力。
Non-enzymatic glucose oxidation to gluconic acid with N, N′-bis(2-hydroxybenzylidineamino) benzene gold (III) complex
In this paper we report non-enzymatic glucose oxidation with N, N′-Bis(2-hydroxybenzylidineamino) benzene gold (III) complex on reduced graphene oxide-gold (rGO-Au) nanoparticle coated modified copper (Cu) electrode. Potassium ferricyanide in 50 mM phosphate buffer solution (pH 7.0) was used as a mediator. The [(Salophen)Au]+ on rGO shows good catalytic property for the oxidation of glucose to gluconic acid (GA). The maximum current response produced by Au3+/Au+ redox potential was monitored by the linear sweep voltammetric method (LSV). As glucose concentration increases the current response at Au+3/Au+ redox potential decreases simultaneously. On catalytic oxidation of glucose to GA by the complex [(Salophen)Au]+, the solution pH reduces to 2.75, which results the decrease of current responses at the Au3+/Au+ working potential.
Graphical abstract
Direct oxidation of glucose to gluconic acid is achieved adopting nonenzytnatic technique by rGO based heterogeneous catalyst is reported in the present study. N,N'-Bis (2-hydroxy benzylidineatnino) benzene gold (III) complex on rGO-Au nanoparticles is used to fabricate the tnodified electrode. The oxidation mechanism is demonstrated. This work showed the potential of using [(Salophen)Au]+ Schiff base complex as a nonenzymatic substitute for glucose oxidize enzyme.
期刊介绍:
Journal of Chemical Sciences is a monthly journal published by the Indian Academy of Sciences. It formed part of the original Proceedings of the Indian Academy of Sciences – Part A, started by the Nobel Laureate Prof C V Raman in 1934, that was split in 1978 into three separate journals. It was renamed as Journal of Chemical Sciences in 2004. The journal publishes original research articles and rapid communications, covering all areas of chemical sciences. A significant feature of the journal is its special issues, brought out from time to time, devoted to conference symposia/proceedings in frontier areas of the subject, held not only in India but also in other countries.